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1、2017 惠州市高三第三次调研考试理科综合化学试题7.下列实验的现象与对应结论均正确的是选项操作现象结论A 将浓硫酸滴到蔗糖表面固体变黑膨胀浓硫酸只表现脱水性B 常温下将Al 片放入浓硝酸中无明显现象Al 与浓硝酸不反应C 将一小块Na 放入无水乙醇中产生气泡Na 能置换出醇羟基中的氢D 将盐酸滴入Na2CO3溶液中产生气泡Cl 的非金属性比C强8 莽草酸是合成达菲的主要原料，其结构简式如图,下列说法正确的是：A.分子式为C7H8O5 B能使溴的四氯化碳溶液褪色C只能发生加成反应和取代反应 D分子中含有2 种官能团9.短周期元素X、Y、Z、W 在元素周期表中的相对位置如图所示，其中W 原子的最
2、外层电子数是最内层电子数的3 倍。下列判断正确的是A原子半径：rWrZrYrXB含 Y 元素的硫酸盐溶液可以和强酸、强碱反应C最简单气态氢化物的热稳定性：ZW DX 的氢化物与X 的最高价氧化物对应的水化物能形成离子化合物10.用 NA表示阿伏加德罗常数的值下列叙述中正确的是（O-16 N-16）A1 mol 甲基(CH3)所含的电子数分别为10NAB标准状况下，22.4 L 四氯化碳中含有C Cl 键的数目为4NA C常温常压下，1 mol 分子式为C2H6O 的有机物中，含有C-O 键的数目为NAD46g 由 NO2和 N2O4组成的混合气体中,含有的原子总数为3NA11.常温时，向一定量
3、的硫酸铜溶液中滴加pH=11 的氨水，当 Cu2+完全沉淀时，消耗氨水的体积为 V，下列说法正确的是（已知KspCu(OH)2=2.210-20）A若将氨水加水稀释，则稀释过程中，c(NH4+)/c(NH3?H2O)始终保持增大B滴加过程中，当溶液中c(Cu2+)=2.210-2 mol/L 时，溶液的 pH=9 C滴加过程中，当溶液的pH=7 时，溶液中 2c(NH4+)=c(SO42-)D若滴加 pH=11 的NaOH 溶液，Cu2+完全沉淀时消耗溶液的体积小于V 12.下列实验设计能够成功的是A检验亚硫酸钠试样是否变质：试样溶解滴加硝酸钡溶液白色沉淀滴加稀盐酸沉淀不溶解 说明试样已变质B
4、除去粗盐中含有的硫酸钙杂质：粗盐溶解足量碳酸钠溶液足量氯化钡溶液 过滤滤液中滴加盐酸蒸发结晶精盐C检验某溶液中是否含有Fe2+：试样滴加硫氰化钾溶液溶液颜色无变化滴加氯水溶液变红色 溶液中含有Fe2+D证明酸性条件H2O2的氧化性比I2强：NaI 溶液30%过氧化氢、稀硝酸淀粉溶液变紫色 氧化性：H2O2I2 13.下列有关NaClO 和 NaCl 混合溶液的叙述正确的是A该溶液中，H、NH4、SO24、I可以大量共存B该溶液中，Ag、K、NO3、NH4可以大量共存C该溶液中,Fe2、Fe3、Cl、NO3可以大量共存D向该溶液中加入浓盐酸，每产生1 molCl2，转移电子约为6.02 1023
5、个27.(14分)肼(N2H4)通常用作火箭的高能燃料，N2O4 作氧化剂。请回答下列问题：已知：N2(g)+2O2(g)=2NO2(g)H=+a kJ/molN2H4(g)+O2(g)=N2(g)+2H2O(g)H=-b kJ/mol2NO2(g)N2O4(g)H=-c kJ/mol写出气态肼在气态N2O4中燃烧生成氮气和气态水的热化学方程式。工业上常用次氯酸钠与过量的氨气反应制备肼，该反应的化学方程式为N2、H2合成氨气为放热反应。800K时向下列起始体积相同的密闭容器中充入2mol N2、3mol H2，甲容器在反应过程中保持压强不变，乙容器保持体积不变，丙是绝热容器，三容器各自建立化学
6、平衡。达到平衡时，平衡常数K甲K乙(填“”“”或“=”)。达到平衡时 N2的浓度 c(N2)乙c(N2)丙(填“”“”或“=”)。对甲、乙、丙三容器的描述，下列说法正确的是A.乙容器气体密度不再变化时，说明此反应已达到平衡状态B.在甲中充入稀有气体He，化学反应速率加快C.将甲中的活塞往下压至原体积的一半，平衡向右移动D.丙容器温度不再变化时说明已达平衡状态氨气通入如图电解装置可以辅助生产NH4NO3，该电解池阴极反应式为。文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档
7、编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK1
8、0H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X
9、2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN
10、1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S
11、9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 Z
12、L4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2
13、E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8在 20mL 0.2mol/L 的NH4NO3溶液中加入 10mL 0.2mol/L NaOH溶液后显碱性，溶液中所有离子浓度大小关系为。28.（15 分）如图A、B、C、D、E 五组仪器（图中a、b、c 表示止水夹）可以根据需要组装成不同实验装置某兴趣小组的同学利用这些实验仪器进行实验，请对其方案进行完善或评价（1）将 B、C、E 相连
14、，用浓硫酸和浓盐酸可制取氯化氢，装在分液漏斗中的试剂是，该实验尾气吸收装置设计有何不妥？；改正后将B、D、E 装置相连，用D 装置中的丁试管收集满氯化氢气体，使烧杯中的水进入试管丁的操作是。（2）将 A、C、E 相连，并在丙中加入适量水，即可制得氯水，将所得氯水分为两份，进行两个实验，实验操作、现象、结论如下表所示：序号实验操作现象结论将氯水滴入品红溶液品红溶液褪色氯气与水反应的产物有漂白性氯水中加入碳酸氢钠粉末有无色气泡产生氯气与水反应的产物有具有酸性请你评价：实验I 推出的相应的结论是否合理？；若不合理，请说明理由，若合理则无需填写）。实验推出的结论是否合理？；若不合理，请说明理由，（若合
15、理则无需填写）。（3）研究表明，用ClO2气体对自来水消毒效果比用Cl2更好市售的一种新型消毒剂含两种成分，分别是 NaClO3和 Na2C2O4两种成分在溶液中混合便产生ClO2，反应的化学方程式为。文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10
16、ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G
17、2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文
18、档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK
19、10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4
20、X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 H
21、N1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3
22、S9U10 ZL4T9G2E1S829.(14 分)氧化铜矿石含有CuO 和 Cu2(OH)2CO3，还含有 Fe2O3、FeO 和 SiO2等。铜、铁是畜禽所必需的微量元素。某饲料厂联合生产硫酸铜和硫酸亚铁工艺流程如下：（1）氧化铜矿石粉碎的目的是。氧化时加入的KMnO4的作用是。（2）写出“酸浸”中Cu2(OH)2CO3发生反应的离子方程式。（3）“中和/过滤”中加入CaCO3的目的是。（4）流程中多处涉及“过滤”，实验室中过滤操作需要使用的玻璃仪器有烧杯、。（5）加入铁屑的作用是、。（6）表 2和图 6 为“烘干粉碎”的试验结果。表 2 中，m 为 CuSO45H2O 晶体的质量，x 为
23、干燥后所得晶体中结晶水的个数。据此可确定由 CuSO45H2O 和 FeSO47H2O 脱水得流程中所示产品的适宜工艺条件分别为，（分别指出两条件的温度和时间）。序号t/h t/m/g x1 3 80 5 4 2 3 160 10 1 3 4 160 10 0.8 4 4 160 5 0 5 5 80 5 3 6 5 160 15 1 硫酸氧化铜矿粉滤液KMnO4铁屑CaCO3CuSO4H2O FeSO43H2O 母液滤渣滤渣滤液滤液酸浸氧化中和/过滤蒸发结晶分离烘干粉碎酸浸过滤置换、还原过滤蒸发结晶分离烘干粉碎氧化焙烧晶体(CuSO4 5H2O)干燥试验表图 6.硫酸亚铁干燥曲线图产品产品文
24、档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK
25、10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4
26、X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 H
27、N1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3
28、S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10
29、ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G
30、2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S834.有机化学基础 (15 分）H是一种香料的成分之一，其结构中含有三个六元环。G的结构简式为，H的合成路线如下（部分产物和反应条件略去）：已知：B中核磁共振氢谱图显示分
31、子中有6 种不同环境的氢原子。D和 G是同系物（1）用系统命名法命名(CH3)2CCH2。（2）AB 反应过程中涉及的反应类型有。（3）G分子中含氧官能团的名称：。（4）写出 B与足量氢氧化钠溶液在加热条件下反应的化学方程式：。（5）写出 F 的结构简式:。（6）同时满足下列3 个条件：与FeCl3溶液发生显色反应；能发生水解反应；苯环上有两个取代基的G的同分异构体有种（不包括立体异构），其中核磁共振氢谱为5 组峰的为（写结构简式）35.物质结构与性质（15 分）氧元素和卤族元素都能形成多种物质，我们可以利用所学物质结构与性质的相关知识去认识和理解。（1）溴的价电子排布式为；PCl3的空间构型
32、为。（2）已知 CsICl2不稳定，受热易分解，倾向于生成晶格能更大的物质，则它按下列式发生:A CsICl2=CsCl+ICl B CsICl2=CsI+Cl2（3）根据下表第一电离能数据判断：最有可能生成较稳定的单核阳离子的卤素原子是氟氯溴碘第一电离能（kJ?mol1）1681 1251 1140 1008（4）下列分子既不存在sp键，也不存在p p键的是A HCl BHF C SO2D SCl2（5）已知 COCl2为平面形，则COCl2中心碳原子的杂化轨道类型为，写出 CO 的等电子体的微粒（写出1 个）。（6）钙在氧气中燃烧时得到一种钙的氧化物晶体，其结构如图所示：由此可判断该钙的氧
33、化物的化学式为已知该氧化物的密度是g?cm3，则晶胞离得最近的两个钙离子间的距离为cm（只要求列算式，不必计算出数值，阿伏加德罗常数为NA）。文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 H
34、N1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3
35、S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10
36、ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G
37、2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文
38、档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK
39、10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8+惠州市 2017 届高三
40、第三次调研考理科综合化学参考答案选择题：（第 7 至 13 题共 7 小题，每题 6 分，单项选择题，小计42 分）7.C 8.B 9.D 10.D 11.A 12.C 13.D 27.(14分）（1）2N2H4(g)+N2O4(g)=3N2(g)+4H2O(g)H=-(a-c+2b)kJ/mol(3分，H错扣 2分)（2）NaClO+2NH3=N2H4+NaCl+H2O(2分，没配平扣 1分)（3）=(1分)(1分)CD（3分，答一个对的得1分）（4）NO+5e-+6H+=NH4+H2O（2分，没有配平扣1分）（5）c(NO3-)c(NH4+)c(Na+)c(OH-)c(H+)(2分)28.
41、(15 分）（1）浓硫酸(2 分），用NaOH 溶液吸收氯化氢易发生倒吸(2 分）;关闭分液漏斗活塞，夹紧止水夹a、b，打开止水夹c，微热试管丁，使试管中气体逸出接触烧杯中的水(2 分）（2）不合理(2 分）；没有实验证明干燥的氯气无漂白性(1 分）。不合理(2 分）；制取的氯气含有HCl，HCl 溶于水后能与碳酸氢钠反应产生气泡(1 分）（3）2NaClO3+Na2C2O4=2ClO2+2Na2CO3（3 分，没有配平扣1 分）29.（14 分）（1）增大接触面积，加快化学反应速率。（2 分）（2）Cu2(OH)2CO34H+2Cu2+3H2OCO2（2 分，没有配平扣1 分）（3）适当降低
42、溶液的酸性，使Fe3+水解成沉淀而除出（2 分）（4）玻璃棒、普通漏斗（2 分，或漏斗）；（5）使母液中Fe3+转化为 Fe2+、除去 Cu2+，提高硫酸亚铁晶体的纯度（2 分，其他合理答案也给分）（6）160、3h；125（5）、4.0h（4 分，每空 2 分，120-130 之间的数据）34.（15 分)（1）2-甲基丙烯（2 分），（2）取代反应、加成反应（2 分），（3）羟基、羧基（2 分）（4）(3 分，没配平扣1分）（5）（2 分），（6）9（2 分）、（2 分）35.（15 分）（1）4s24p5（2 分）、三角锥形（1 分）；（2）A（2 分）；（3）碘（2 分）（4）D（2
43、分；（5）sp2杂化（1 分）；N2（1 分）（6）CaO2（2 分）；cm（2 分）文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:
44、CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5
45、B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8
46、 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3
47、C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U1
48、0 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T
49、9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S
50、8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码:CK10H5B4X2Z8 HN1N3C3S9U10 ZL4T9G2E1S8文档编码: