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1、?1?14?2?14?H 1 Li 7 C 12 O 16 Na 23 Al 27 Si 28 S 32 Cu 64?1?A.?“?”?“?”?42CuSO5H O?B?“?”?C?“?”?D?“?”?“?”?2.?A?Hg?Ag?Sn?Cu?B?C?D?222HOH O233NNHNOHNO?3?A?4CuSO?2+2+323 42Cu+4NH)H O=Cu(NH+4H OB?224H C O?4KMnO?-+2+2244225H C O+2MnO+6H=2Mn+10CO+8H O?C?2+22Pb+2H O 2ePb=O+4H?D?2Na S?2SO?2-2223S+2SO+2H O=H
2、S+2HSO?4.2-?-4-?A?X?Y?B?C?X?D?1 mol Z?6 mol 2H?5.?NA?A?1.28 g?2SO?S?A0.04NB?0.3 mol?325Co NHCl Cl?-Cl?A0.9NC?11.2 L2 N?3NH?AN?3?14?4?14?D?pH?11?NaCN?-OH?A0.001N6.?3KIO?22H O?“?”?.?A?222I H OB?22 mol O?-e?A8NC?22H O?2ID?“?”?7?W?X?Y?Z?M?M?Y?Z?A?XYZ?B?YM?C?W?Y?Z?D?P?Q?W?X?Y?Z?8?8?W?X?Y?Z?M?N?W?X?Y?Z?M?
3、Y?M?N?W?6?A?W?X?YB?N?M?Y?ZC?N?ZD?Y?N?Y?N?9?2BaH?2BaH?2BaH?A?I?B?II?C?IID?III?2BaH?10.?24226C Hg+Hg=C Hg H?Au?A?B?AuF?-1198.24 kJ mol?C?1?2D?+3AuPF?公众号【永久学堂】微信：yjxt6699 快速更新?5?14?6?14?11.?4MnSO?4ZnSO?3MnCO?sp()MnSK?102 10?sp()ZnSK?242 10?A?“?”?MnSB?“?”?ZnSC?“?”?2332342MnHCONHH O=MnCONHH O?D?“?”?442NH
4、SO?32NHH O?43NH HCO12?a?8S?Nalon?+Na?8216Na+S8Na S?A?b?B?a?2-+222S+24 e+2 Na=Na Sxxxx?C?+Na?b?a?D?0.03 mol?0.69 g13?1-?9-?1-?9-?(?1)?(?)?2?()A.?a?B.?2?C.?D.?40?0.5 MPa14.?0.1000 mol/L3NaHCO?100 mL?2Ba OH?lgc(2+Ba)?3NaHCO?V(3NaHCO)?A?2Ba OH?0.01 mol/LB?Ksp(3BaCO)?8.410?7?14?8?14?C?c?3HCO?23CO?D?d?b?1
5、5.?Acetophenone?Friedel?Craffs?3332CH COOHAlClCH COOAlClHCl?/?/?/1g mL?731401.082?5.580.50.879?20.52021.028?1?_?2?_?3?3?_?10%?NaOH?_?a.?b.?c.?10%?NaOH?4?2?_?A.?B.?C.?5?130?_?_?6?3AlCl?3AlCl?1?2CaCl?3AlCl?_?_?7?_?1?公众号【永久学堂】微信：yjxt6699 _ _?_ _?快速更新?9?14?10?14?16.?Pd/C?Fe?Cu?2PdCl?Pd?“?”?242N HH O?PdO
6、?Pd?3:1?1?“?”?_?2?24HPdCl?A?HCl?3HNO?3?“?pH=a”?pH=a?a?pH?b?b a?“?”?“?”?“?”?sp3Fe OHK?=392.8 10?sp2Cu OHK?=202.2 10?224.7?lg4.7=0.7?4?“?”?324Pd NHCl?322Pd NHCl?5?22PdH2PdHxsxgs?-3 g cm?n?R=3cm?R?1 g?6?Pd?Se?17.“?”?I?222COgHgCO gH O?H1?+41.2 kJmol?1?II?23CO g2HgCH OH g?H2?90.6 kJmol?1?III?2232COg3HgCH
7、 OH gH O g?H3?1?III?H3?_?2?I?III?_?A.?3CH OH?B.?3(CH OH)(CO)nn?C.?III?I?D.?2H?2CO?2CO?3?II?“*”?11?14?12?14?4?23In O?2CO?23In O?O?23-In Ox?23In O?In?In?Al?I?In?_?2H O(g)?3CH OH?2H?5?1 mol 2CO(g)?3 mol 2H(g)?I?III?2CO?a?CO?b mol?III?Kx?a?b?A gB gC gD gmnpq?(C)(D)(A)(B)pqmnxxxxxK?x?18.?Mo?P?HCHO?1?P?_?
8、2?442NHHPO?_?P?_?3?d?p?d?p-d?33PF PH?_?4?_?5?2MoS?90?60?a?b?c?Mo?S?Mo?S?rMo?rS?_?19?H?公众号【永久学堂】微信：yjxt6699 快速更新?13?14?14?14?R?H?1?A?2?AB?3?C?4?DE?5?E?F?6?A?B?9105C H OB?3NaHCO?D?CC?F?D?H?7?D?3FeCl?5?2:2:2:1:1?1?14?2?14?1.?C?A?42CuSO5H O?A?B?“?”?B?C?“?”?C?D?“?”?D?C?2.?A?A?A?B?Fe?34Fe O?34Fe O?B?C?-Cl
9、?4KMnO?C?D?NO?NO?2NO?2NO?D?A?3.?B?A?4CuSO?2+3242=Cu+2NHH OCu OH=+2NH?2+2+323 42Cu+4NH)H O=Cu(NH+4H O?A?B?4KMnO?224H C O?224H C O?-+2+242425H C O+2MnO+6H=2Mn+10CO+?28H O?B?C?4PbSO?+24224=PbSO+2H O 2ePbO+4HSO=?C?D?2Na S?2SO?S?3NaHSO?2-2232S+5SO+2H O=3S+4HSO?D?B?4.?B?A?X?3?Y?2?A?B?H?B?C?X?C?D?1:3?1:1?Z
10、?2?1?1 mol?7 mol 2H?D?B?5.?C?A?1.28 g?0.02 mol?24Cu2H SOCuSOSO2H O?2SO?0.02 mol?S?=162 2=12?S?A0.02N?A?B?0.3 mol?325Co NHCl Cl?-Cl?A0.6N?B?C?211.2 L N?N2?0.5 mol?223N3H2NH?2 H2NH?3NH?1 mol?AN?C?D?Kw=1410?pH=11?c(-OH)=0.001 mol/L?-OH?D?C?6.?D?3?14?4?14?322242KIO+5H O+H SO=224I+K SO+226H O+5O?2222432I
11、+5H O+K SO=2KIO+4H O+24H SO?A?22H O?222H O I?A?B?221 mol H O?21 mol O?2 mol?22 mol O?e?4 NA?B?C?22H O?22H O?2O?C?D?+?222H O?222H O+O?D?D?7.?D?W?X?Y?Z?M?W?1?W-X?W?H?F?X?X?C?Si?Y?Y?N?P?M?Y?Z?M?Y?Z?Z?1?X=Z?X-Z?Z?O?Y?N?X?C?M?Y?Z?M?P?W?X?C?W?H?A?X?C?Y?N?Z?O?X?Y?Z?A?B?Y?N?M?P?P?N?Y?M?B?C?W?H?Y?N?Z?O?H?N?O
12、?C?D?P?Q?W?H?H?8?D?D?8.?D?W?6?W?C?W?X?Y?Z?M?N?W?X?Y?Z?M?X?N?Y?O?Z?F?Y?6?Y?M?N?M?Na?N?Cl?A?W?C?X?N?Y?O?N?2p?N?O?N?O?C?A?B?Y?O?Z?F?M?Na?N?Cl?2-O?-F?+Na?2?Y?Z?M?-Cl?3?2-O?-F?+Na?N?Y?Z?M?B?C?Z?F?HF?N?Cl?HCl?HF?Z?N?C?D?Y?O?Y?O2?O3?N?Cl?N?Cl2?ClO2?O3?Cl2?ClO2?D?D?9.?C?C?+H?2H?Fe?Fe?2+Fe?2H?2H?Ba?2BaH?A?I?
13、Fe?2+=Fe 2eFe?OH?2+Fe?OH?2Fe OH?2Fe OH?A?B?2BaH?2H?B?C?III?2BaH?II?III?III?C?D?Ba?2BaH?2H?2BaH?D?C?10.?D?A?A?快速更新?5?14?6?14?B?AuF?-1109.34 kJ mol?B?C?1?2?1?2?C?D?AuF?3AuPF?-1109.34 kJ mol?-1104.1 kJ mol?AuF?3AuPF?3AuPF?D?D?11.?B?4MnSO?4ZnSO?3MnCO?“?”?spK(MnS)?102 10?spK(ZnS)?242 10?MnS?ZnS?MnS?ZnS?3
14、2NHH O?43NH HCO?2+Mn?3MnCO?A?4ZnSO?2+Zn?MnS?A?B?A?ZnS?MnS?B?C?“?”?32NHH O?43NH HCO?23MnHCO?33422NHH O=MnCH OONH?C?D?C?“?”?424NHSO?32NHH O?43NH HCO?D?B?12.?C?A?b?a?b?a?A?B?a?2-+222S+24 e+2 Na=Na Sxxxx?B?C?Nalon?+Na?+Na?a?b?C?D?+NaeNa?0.03 mol?0.03 mol23 g/mol?0.69 g?D?C?13.?B?A.?1-?9-?1:1?a?A?B.40?B?
15、C.?9-?9-?-1,18?C?D.?40?0.5 MPa?D?B?14.?C?a?b?32Ba OH+NaHCO=32NaOH+BaCO+H O?b?c?3232NaOH+NaHCO=Na CO+H O?c?3NaHCO?A?V(3NaHCO)?10 mL?2Ba OH?3NaHCO?3BaCO?n?2Ba OH=n(3NaHCO)?c?2Ba OH=0.01 mol/L?A?B?V(3NaHCO)?10 mL?2Ba OH?3NaHCO?3BaCO?c(2+Ba)?c(2-3CO)?10?4.2mol/L?3sp(BaCO)K?4.228.41010?B?C?C?23Na CO?0.01
16、 mol/L?0.1 mol/L?7?14?8?14?3NaHCO?-3HCO?2-3CO?C?D?d?23Na CO?3NaHCO?b?NaOH?d?B?D?C?15.?1?2?3?cab?4?A?5?6?A?3AlCl?7?81.3%?1?2?3?3?10%?NaOH?NaOH?cab?4?80.5?A?5?80?202?6?2CaCl?2CaCl?A?3AlCl?A?3AlCl?7?4ml 1.082g/ml102g/mol?0.042 mol?16 ml 0.879 g/ml78 g/mol?0.18 mol?4.1 g0.042 mol 120 g/mol?100%81.3%?81.
17、3%?16.?1?Fe?Cu?Pd?2?6:1?2.5 h?90?3?32NHH O?6.7?4?324Pd NHCl?323242Pd NHClaqPd NHCls+?32NHaq?NH3?322Pd NHCl?5?n?6?2PdSe?Fe?Cu?Fe?Cu?Pd?“?”?242N HH O?PdO?Pd?Pd?Pd?24HPdCl?NO?pH?234Pd NH?3+Fe?2+Cu?3Fe OH?2Cu OH?322Pd NHCl?2PdCl?Pd?1?Fe?Cu?Fe?Cu?Pd?公众号【永久学堂】微信：yjxt6699?快速更新?9?14?10?14?Fe?Cu?Pd?2?3:1?24H
18、PdCl?A?A?NO?3Pd+2HNO3+?24212HCl=3HPdCl+2NO+4H O?HCl?3HNO?6:1?2.5 h?90?6:1?2.5 h?90?3?pH?Cu2+?2Cu OH?c(OH?)?sp25Cu OH10K?2052.2 1010?mol/L4.710?8 mol/L?c(+H)?148104.7 10?mol/L?pH?14?8+lg4.76.7?sp3Fe OHK?=392.8 10?sp2Cu OHK?pH?32NHH O?6.7?4?“?”?324Pd NHCl?323242Pd NHClaqPd NHCls+?32NHaq?3NH?322Pd NHCl
19、?324Pd NHCl?323242Pd NHClaqPd NHCls+?32NHaq?NH3?322Pd NHCl?5?1 g Pd?31 gg /cm?H2?n31 gg /cm?n?mL?n?6?Pd?4?Se?2?2PdSe?2PdSe?17.?1?149.4 kJ mol?2?BC?3?22=3CO*+2HHCO*+H2gg?4?215s 5p?2H Og?232In O+Hx232In O+H Oxx?2H?23In O?5?23()(422)(1)(332)a ababaab?1?312HHH?149.4 kJ mol?,?149.4 kJ mol?2?3CH OH?A?I?II
20、I?I?III?3(CH OH)(CO)nn?B?III?2CO?2H?2H O?I?C?2H?2CO?2H?2CO?D?BC?3?2?2CO*+2Hg?23HCO*+H2g?22=3CO*+2HHCO*+H2gg?4?In?IIIA?215s 5p?215s 5p?2H?23In O?O?2H O?2H O g?232In O+Hx232In O+H Oxx?2H O g?232In O+Hx232In O+H Oxx?11?14?12?14?2H?2322=In O+3H2In+3H=O?23In O?2H?23In O?5?21 mol COg?23 mol Hg?I?III?2CO?a
21、?CO?molb?6?22COg+Hg?2CO g+H O g?CO?(mol)b b b b?22CO+3Hgg?32CH OH g+H O g?(mol)?ab?ab?ab?ab?2COn=?1a?mol?2Hn=?332ab?mol?3CH OHn=?ab?mol?2H On=a mol?n?1a?mol+?332ab?mol+?ab?mol+a mol+b mol?422ab?mol?III?323322(CH OH)(H O)4224221332(CO)(H)()422422xabaxxababaabxxababK?a42242 22(H O)2?32(H)32(3333(42(33
22、 33342 223()(422)(1)(332)a ababaab?23()(422)(1)(332)a ababaab?18.?1?2?3sp?3?P?3d?F?2p?p-d?3PH?4?MoP?5?6?33MoS2442433100%32rrm n?1?P?2?N?H?P?O?O?H?+4NH?2-4HPO?P?0?4?P?3sp?3sp?3?P?3d?F?2p?p-d?3PH?P?3d?F?2p?p-d?3PH?4?Mo?P?P?818+814+212?4?Mo?4?Mo?MoP?MoP?5?S?Mo?3?2MoS?Mo?S?6?m?n?90?60?232m n?2?Mo?4?S?33
23、MoS2442433100%32rrm n?6?33MoS2442433100%32rrm n?19.?1?2?3?4?5?6?D?7?13?1?A?2?A?OHCCOOH?B?公众号【永久学堂】微信：yjxt6699 快速更新?13?14?14?14?3?BC?C?4?D?E?DE?D?H?DE?5?6?A?B?C9H10O5?A?B?C?NaHCO3?CO2?NaHCO3?C?B?C?F?C?D?H?H?H?D?D?7?D?3FeCl?D?D?5?D?2CH OOCH?OH?3?D?OH?3CH?OOCH?10?F?13?5?2:2:2:1:1?13?公众号【永久学堂】微信：yjxt6699?永久学堂】微信：yjxt6699 学堂】微信：yjxt6699?快速更新