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1、外 文 翻 译毕业设计题目： 纱线喷射染色控制系统设计 原文1：Deep-colour vat dyeing of cotton knit fabric on modified jet dyeing machine 译文1：改进的喷射染色机上的深颜色还原染色棉布织物 原文 2： Analysis of the factors influencing dye uptake on jet dyeing equipment 译文 2：喷射染色设备上影响染料吸收因素的分析 Deep-colour vat dyeing of cotton knit fabric on a modified jet dy
2、eing machineToday, cotton clothes are dyed with vat dyes in a continuous system, with stepwise operations of reducing the dye to leuco form, soaking the clothes in the bath under a nitrogen atmosphere, and then holding the clothes in an airatmosphere for oxidation. Soaping, washing, and application
3、of various auxiliary agents follow continuously to finish the processing.However, cotton knit fabric, which is not put into the continuous system because of its overstretching on the conveyor, must be vat dyed in a batch system, where inhomogeneous reduction and oxidation of the dyed fabric often le
4、ad to some defects in the product. This report describes a new method for stable vat dyeing of cotton knit fabric in a batch, especially deep-colour dyeing, using a modified jet dyeing machine operating without the use of nitrogen gas to purge oxygen.Before designing the mechanical system for deep-c
5、olour dyeing with vat dyes, which has not been practiced commercially until now, preliminary information on dye diffusion in cellulosic substrates was obtained using the cellophane film roll method, by which dye uptake at the surface and the diffusion behaviour of the dye within the roll were measur
6、ed quantitatively. As with other dyeing processes, it is desirable in vat dyeing that the temperature be as high as possible in order to reduce dyeing and processing time. However, increasing the temperature tends to result in unevenness in the dyed fabric, resulting in various defects in the produc
7、t. The dyeing conditions, including the concentrations of reducing agent, sodium hydroxide, and the weight ratio of used dye to fabric, were examined by test dyeing in an Erlenmeyer flask under a nitrogen atmosphere. The possibilities of lowering the liquor ratio, the dyeing temperature, and the dur
8、ation of each process were also examined in the flask experiment.The core technology for successful batch dyeing on a production scale consists in completely reducing the dye to leuco form for molecular dispersion in the dyeing liquor, preventing air penetration from outside into the reducing liquor
9、, making the contact of the knit fabric with the liquor as even as possible, exposing it gradually to overflowing water for gentle and homogeneous oxidation initially, and then completing the oxidation with the replaced oxidizing liquor. Any inhomogeneous contact of the fabric with the liquor leads
10、to faults such as spot stains due to contact with undispersed leuco dyes, streaking due to insufficient evenness of contact of the knit with the dyeing liquor and unlacing of the rope during circulation, and spread stains due to uneven oxidation.These problems are crucially serious in vat dyeing on
11、a jet dyeing machine. Rigorous airtightness is necessary. The speeds of the knit fabric and liquor circulation should be meticulously regulated, and the introduction of solutions of reducing agent and dye or oxidising agent into the dyeing liquor should be controlled so as to make the contact of the
12、 fabric with them as even as possible. To overcome these restrictions, necessary modifications to the dyeing machine are proposed in this study. In addition, monitoring of the redox potential and pH of the liquor in each process helps in following the progress of dyeing in situ and in making each op
13、eration controllable. These measurements are also useful in confirming the completion of processes of dyeing with leuco dyes and oxidation of the dyed fabric.The present study first reports preliminary investigations on dyeing in a Erlenmeyer flask and with the film roll method as a model for cotton
14、 knit dyeing. The measurements were performed for Indanthren Direct Black RB Coll.at 60, 70, and 80 C. Feasible conditions for stable production were established by referring to pre-examined data for each parameter, e.g. the concentration of reducing agent, sodium hydrosulfite and sodium hydroxide,
15、the liquor ratio of dyeing, and the oxidation process.Based on the data obtained by the Erlenmeyer test, the film roll method, and dyeing on the modified test jet machine for 12 kg of cotton knit fabric, reasonable operating conditions were established for vat dyeing on a 80 kg scale. Modifications
16、were made to the conventional jet dyeing machine to realise stepwise operations with the dyeing liquor, oxidation with water, and final oxidation with oxidising agent. After dyeing, soaping was carried out twice with foamless soap. We report that high quality of dyed fabric and reproducibility have
17、been attained consistently on the modified machine under production conditions for the past 2 years.ExperimentalMaterialsCotton knit fabric (30/1 cotton, 100% knit fabric, 24G-26 is the spec of a circular knittngmabhine. If the units are changed into cm unit, the number of needles, 9.49/cm (24G) and
18、 the diameter is 66.04cm (26) ) was purchased from Verite Co. Ltd, Japan. The fabric was scoured and bleached with hydrogen peroxide under standard conditions. Cellophane film of 0.043 mm thickness, supplied by Futamura Chemical Co. Ltd, Japan, was used after soaking in deionised water for 1 h at am
19、bient temperature.Dyes and chemicalsIndanthren Direct Black RB Coll. (CI Vat Black 9) was obtained from DyStar (Japan) and used as received. The structural formula is shown in Figure 1. Sodium hydrosulfite and sodium hydroxide were supplied by Wako Pure Chemical Industries, Ltd (Japan). Sodium meta-
20、benzene sulfonate (Ludigol) was purchased from BASF (Japan). A scouring agent (Neonol HT: ethylene glycol mono-n-butyl ether) and a softener (S-M1: alkylether X and potassium phosphate mixture) were supplied by Fushimi Chemicals Co. Ltd (Japan). Soaping, which was required to be foamless in the jet
21、dyeing machine, was carried out 2 times with a 1:1 mixture (by weight) of sodium tripolyphosphate and sodium meta-silicate. All the reagents were for production use. For the Erlenmeyer and the film roll expriments, deionised water was used, and for the production experiments, distilled water was use
22、d.Film roll methodSekido and Matsui were the first to report and give a full account of the cellophane film roll method to study the diffusion coefficients of some vat dyes . Figure 2 shows the assembly of the roll of cellophane film. The roll was put in a 50 ml solution containing 0.0056 g of the d
23、ye, 0.14 g of sodium hydroxide, and 0.1 g of sodium hydrosulfite in a test tube, and stoppered tightly under a nitrogen atmosphere. The tube was placed in a vibrator at 60, 70, and 80 C and shaken for 72 h. After dyeing, the rolled film was unrolled quickly, washed lightly with water, kept exposed t
24、o air for 1 h, and used for dye concentration measurement. Figure 3 shows the unrolled films. The absorbance at the maximum absorption wavelength (520 nm) for each film layer was measured on a UV-vis spectrophotometer (UV-2450; Shimadzu, Japan) for the dye concentrations of the respective layers. No
25、te that the dye concentration in each layer shown in Figure 4a was as dyed and oxidised, but not as soaped. The dye concentrations on the outer surface and inner surface of the first layer of the film roll, which were measured on a Shimadzu ATR-FTIR instrument by taking 100 spectra, are shown in Fig
26、ure 4b, where a large excess of dye adsorption is shown at the outer surface of the layer.Determination of the dyeing conditions in the jet dyeing machineThe concentrations of dye, sodium hydrosulfite, sodium hydroxide, and sodium meta-nitrobenzene sulfate, the liquor ratios, and the diagrams of tem
27、peratures and times for respective operations were pre-examined in the Erlenmeyer flask experiments. With a liquor ratio of 1:15, a dyeing temperature of 80 C, and respective operating times, the reproducibility of dyeing was confirmed on the test jet machine, and the conditions were transferred top
28、roduction-scale dyeing on the modified jet machine.Modification of the conventional jet dyeing machineFor our purposes, to use the machine for vat dyeing without using nitrogen gas, five principal modifications to the jet dyeing machine were necessary: (1) provision of controllable airtightness agai
29、nst oxygen penetration into the dyeing apparatus from outside air in respective operations; (2)provision of a probe and ORP meter (Yokogawa, Japan) for measurements of the redox potential and pH in the circulating liquids; (3) provision of an inlet for feeding of concentrated solutions of reducing a
30、nd oxidising agents; (4) provision of an inlet and outlet for overflowing water; (5) attachment of a small inspection window for occasional monitoring of the inside when necessary, aside from the round window for fabric set-in. The Hisaka (Japan) circular rapid model CUT-MR-M for the test dyeing of
31、25 kg of fabric and CUT-MR-1L for 100 kg dyeing were modified along these lines. Figure 5 presents a drawing of the modified Hisaka CUT-MR-1L jet dyeing machine. The sealing of the two windows was made airtight by using high-performance silicone rubber and Teflon_. The absence of penetration of oxyg
32、en from outside air was confirmed under operating conditions by measuring the stable redox potential of the liquid containing sodium hydrosulfite. The overflow water was pressurised to 1.3 kgf m-2 to pour water into the slightly pressurised can body.Results and DiscussionCalculation of the approxima
33、te diffusion coefficient (Da)The distribution of dye in layers of film roll dyed at 60, 70,and 80 C was measured to seek the most effective dyeing temperature. Figure 3 presents photos of unrolled films dyed at these temperatures. The distributions of vat dye in respective layers of the film roll wi
34、th a solution containing 0.010 g l-1 of dye, 8.4 g l-1 of sodium hydroxide, and 6.0 g l-1 of sodium hydrosulfite are shown. After unrolling, the films were washed lightly with water. It can seen in Figure 4a that the dye concentrations in the first layers dyed at the three temperatures are excessive
35、ly high compared with those of the second and subsequent layers. Generally, vat dyes are known to have a dyeing property known as strike dyeing, i.e. a very rapid degree of dye exhaustion and a very low rate of diffusion within the fibre . To find the cause of the high concentrations in the first la
36、yers, the dye concentrations on both surfaces of the first layers dyed at 80 C were measured on an ATR-IR instrument with 100-fold repetition. Figure 4b shows the spectra of both sides at around 1600 cm-1, corresponding to the overlapped absorptions by the stretching of C=O and C=C of the aromatic r
37、ings . It can be seen from Figure 4b that the absorptions are remarkably uneven at the two surfaces of the first layer, indicating excess deposition of the dye on the outer surface. Apparently this is the origin of strike dyeing,and it has been pointed out that diffusion of the dye inside the fibre
38、is important for the level dyeing of cotton . The values of the diffusion coefficient, Da, inside the film roll were estimated using the concentration data for the second and subsequent layers. For vat dyeing of cellophane, Sekido and Matsui reported a method for estimating the approximate diffusion
39、 coefficient.They showed that the concentration ratios Ci + 1/Ci are expressed as Ci + 1/ Ci =(i -i + 1) / ( i 1 -i), where i = ierfc i. Parameter is related to Da by the equationwhere Da is the approximate diffusion coefficient, cm2 min-1, is the film thickness, cm, and t is the time,min. They gave
40、 a group of curves for Ci + 1/Ci, where i = 1, 2, 3, . . ., vs , on which Da values were estimated from two successive Ci values from the second layer inward. Table 1 shows Da values observed with the three concentrations of reducing agent at the three temperatures. The Da values increase greatly wi
41、th temperature, about 4.5-fold from 60 to 80 C. As anticipated, dyeing at a higher temperature isadvantageous for reduced striking and also for saving dyeing time.Model dyeing by the film roll method for setting production conditionsThe dye concentration was adjusted so as to obtain a satisfactory d
42、eep black colour. The concentration of reducing agent was set at 1.2 times the dye in molar ratio to consume oxygen in the air space of the machine.As found in Table 1, the ratios of Da values for the dye at 60, 70, and 80 C were found to be 1:2.2:4.5. Equilibrium sorptions, however, contain excess
43、concentrations on the outer surfaces of the film and hence, in productive dyeing, probably on the surfaces of cotton filaments. As this phenomenon cannot be avoided in dyeing and is undoubtedly associated with various fastnesses of the dyed knit fabric, a practical solution to diminishing the effect
44、 was adopted by applying effective soaping 2 times. At 60, 70, and 80 C, the apparent concentrations on the first layer become ca. 2:1.3:1, suggesting that the higher temperature is also advantageous for reducing the surface deposition. With these considerations, the dyeing temperature was set at 80
45、 C for 40 min.Measurements of the redox potential and pH under dyeingconditions in the modified jet machineTo monitor the progress of dyeing in situ, the redox potential and pH were measured for the dyeing liquid,overflowing water, and oxidising liquid. Figures 68 show the changes in the two paramet
46、ers in respective processes with time. Figure 6 shows that the values for reducing liquid containing the dye, 8 g l-1 of sodium hydroxide, and 8 g l-1 of sodium hydrosulfite decrease to stable values after 40 min of dyeing. Figure 7 shows that stable values arereached after the addition of 4800 l of
47、 overflowing water,indicating that the reducing liquid is washed out and the oxidation potential takes the value of that of the overflowing water. Figure 8 shows the decreases in the two parameters on the addition of oxidising liquor. It can seen that after 30 min both parameters decrease to constan
48、t values, indicating that oxidation has been completed. These measurements confirmed in situ that the respective steps had been completed, and that the set time courses of the successive steps were adequate.Operation of modified jet dyeing machines Dyeing operations were performed with two modified
49、machines to test and establish production conditions. Figure 9 shows a temperature control diagram for the successive processes. Liquor containing reducing agent in 20% excess is introduced for reduction of the dye from the service tank, and circulated for 5 min. Then 15 kg of prescoured fabric is introduced, dye solution is fed from the inlet, and the fabric and l