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1、REACH 151 项项 SVHC 清单清单 155 kinds of substances in the SVHC list 2013年12月16日，欧盟化学品管理局(ECHA)已正式将7种物质纳入需授权高度关注物质候选清单(SVHC清单)，这是REACH法规实施以后公布的第十份SVHC清单。目前，SVHC 清单中共有 151 种物质。December 16,2013,the European Chemicals Agency(ECHA)had added 7 chemical substances to the Candidate List of Substances of Very Hi
2、gh Concern(SVHC)for Authorization,this is the 10nd edition of SVHC list since the enforcement of REACH regulation.Currently,a total of 151 kinds of substances were in the SVHC list.第一批第一批 SVHC 清单清单(2008 年年 10 月月 28 日公布，共日公布，共 15 种种)The First Batch of SVHC List(Published on Oct 28,2008，total 15)序号 NO
3、.物质名称 Substance name EC 号 EC No CAS 号 CAS No 高关注属性 SVHC property 用途 Use 1 4,4-二氨基二苯甲烷 4,4-Diaminodiphenylmethane 202-974-4 101-77-9 致癌 Carcinogenic PCB 中环氧树脂的固化剂、PU 配制品、服装中的偶氮染料。Curing agent for epoxy resin in PCB,preparation of PU,azo dyes in garments.2 二甲苯麝香 5-tert-butyl-2,4,6-trinitro-m-xylene 20
4、1-329-4 81-15-2 vPvB 化妆品和皂用香料。Cosmetics and soap perfumes.3 短链氯化石蜡(SCCPs)Alkanes,C10-13 chloro(short chain chlorinated paraffins,SCCP)287-476-5 85535-84-8 持久性，生物累积性和毒性的物质 PBT 皮革中的涂层、PVC 和氯化橡胶中的增塑剂，纺织品和塑料的阻燃剂 Leather coating,plasticizer in PVC and chlorinated rubber,flame retardant in plastic&textile
5、s 4 蒽 Anthracene 204-371-1 120-12-7 持久性，生物累积性和毒性的物质 PBT 染料来源 Source of dyestuff 序号 NO.物质名称 Substance name EC 号 EC No CAS 号 CAS No 高关注属性 SVHC property 用途 Use 5 五氧化二砷 Diarsenic pentaoxide 215-116-9 1303-28-2 致癌 Carcinogenic 杀虫剂、除草剂、木材防腐剂、涂彩杯子、染料和颜料 Insecticides,weed killer,wood preservatives,coloured
6、glass,dyeing and printing 6 三氧化二砷 Diarsenic trioxide 215-481-4 1327-53-3 致癌 Carcinogenic 除草剂、木材防腐剂、特殊玻璃的加工 Weed killers,timber preservatives,manufacture of special glass 7 邻苯二甲酸二辛酯(DEHP)Bis(2-ethylhexyl)phthalate 204-211-0 117-81-7 致生殖毒性 Toxic for reproduction PVC，树脂等塑料制品的增塑剂 Plasticizer for resin,P
7、VC,blister 8 三丁基氧化锡 Bis(tributyltin)oxide(TBTO)200-268-0 56-35-9 持久性，生物累积性和毒性的物质 PBT 杀虫剂，涂料中的杀真菌剂 Pesticide,fungicide in paint 9 邻苯二甲酸二丁酯 Benzyl butyl phthalate(BBP)201-622-7 85-68-7 致生殖毒性 Toxic for reproduction 用作树脂、PVC、丙烯酸树脂的增塑剂 Plasticizer for resin,PVC,acrylics 10 二氯化钴 Cobalt dichloride 231-589-
8、4 7646-79-9 致生殖毒性 Toxic for reproduction 生产其他钴化合物的中间体，轮胎附着力添加剂，有机纺织染料，涂料干燥剂。此外，它是用来在表面处理过程中，作为水处理/缓蚀化学色素或无机颜料与釉料，玻璃，陶瓷制品的生产，湿度指示剂 Mainly used as intermediate in the manufacture of other cobalt compounds,in tyre adhesion additives,organic textile dyes,and drying agents for paints.Furthermore it is us
9、ed in surface treatment processes,as water treatment/corrosion inhibition chemical,as colourant or for discolouring in the production of inorganic pigments&frits,glass,and ceramic 序号 NO.物质名称 Substance name EC 号 EC No CAS 号 CAS No 高关注属性 SVHC property 用途 Use ware,in varistors and magnets,as well as in
10、 humidity indicators.11 邻苯二甲酸二丁酯 Dibutyl phthalate(DBP)201-557-4 84-74-2 致生殖毒性 Toxic for reproduction 粘合剂和纸张涂层的增塑剂，纺织品中的杀虫剂 Plasticizer,in adhesives and paper coatings;insect repellent for textiles 12 六溴环十二烷以及所有主要的非对映异构体Hexabromocyclododecane(HBCDD)and all major diastereoisomers identified(-HBCDD,-H
11、BCDD,-HBCDD)247-148-4 221-695-9 25637-99-4;3194-556(134237-51-7 134237-50-6,134237-52-8)持久性，生物累积性和毒性的物质 PBT 纺织品和 HIPS 中的阻燃剂 Flame retardant used in HIPS and textiles 13 酸式砷酸铅 Lead hydrogen arsenate 232-064-2 7784-40-9 致癌及生殖毒性 Carcinogenic,toxic for reproduction 驱虫剂 Insectides 14 重铬酸钠 Sodium dichroma
12、te 234-190-3 7789-12-0 10588-01-9 致癌、致突变、致生殖毒性 CMR 皮革中的铬镀，颜料阻蚀剂，纺织染料工业中的媒染剂 Chrome-tanning of leather,corrosion inhibitor in paints,mordant in textile dyeing process 15 三乙基砷酸酯 Triethyl arsenate 427-700-2 15606-95-8 致癌 Carcinogenic 半导体的中间产物 Intermediates for semi-conductor 第二批第二批 SVHC 清单清单(2010 年年 1
13、月月 13 日公布，共日公布，共 13 种种)The Second Batch of SVHC List(Published on Jan 13,2010,total 13)序号 NO.物质名称 Substance name EC 号 EC No CAS 号 CAS No 高关注属性 SVHC property 用途 Use 16 蒽油 Anthracene oil 292-602-7 90640-80-5 PBT and vPvB 主要用于制造其他物质，如提炼蒽、碳黑，也用于炸药的还原促进剂，作为燃料的组成部分以及海洋捕捞、防腐。Mainly in the manufacture of ot
14、her substances,such as refined anthracene,carbon black,restore promoter,part of the fuel and marine fishing,anti-corrosion 17 蒽油,蒽糊,轻油 Anthracene oil,anthracene paste,distn.Lights 295-278-5 91995-17-4 PBT and vPvB 18 蒽油,蒽糊,蒽馏分 Anthracene oil,anthracene paste,anthracene fraction 295-275-9 91995-15-2
15、PBT and vPvB 19 蒽油,含蒽少量 Anthracene oil,anthracene-low 292-604-8 90640-82-7 PBT and vPvB 20 蒽油,蒽糊 Anthracene oil,anthracene paste 292-603-2 90640-81-6 PBT and vPvB 21 高温煤沥青 Pitch,coal tar,high temp.266-028-2 65996-93-2 PBT and vPvB 涂料，防潮层 Paint,moisture seal 22 三(2-氯乙基)磷酸酯（TCEP）Tris(2-chloroethyl)pho
16、sphate 204-118-5 115-96-8 致癌、致突变、致生殖毒性 MR 阻燃剂、阻燃性增塑剂 Flame retardant,plasticizer 23 2,4-二硝基甲苯 2,4-Dinitrotoluene(2,4-DNT)204-450-0 121-14-2 致癌、致突变、致生殖毒性 CMR 用于制造炸药、聚氨酯塑料、有机体合成和染料 Manufacture of explosives,polyurethane plastics,organic synthesis,dyes 24 邻苯二甲酸二异丁酯 201-553-2 84-69-5 致癌、致突变、致生殖增塑剂 序号 NO
17、.物质名称 Substance name EC 号 EC No CAS 号 CAS No 高关注属性 SVHC property 用途 Use Diisobutyl phthalate（DIBP）毒性 CMR Plasticizer 25 钼铬红、钼红(C.I.颜料红 104)Lead chromate molybdate sulfate red(C.I.Pigment Red 104)235-759-9 12656-85-8 致癌、致突变、致生殖毒性 CMR 用作涂料，颜料和塑料的添加剂 Used as additives for painting and coatings,printing
18、 inks and in plastics 26 铬酸铅黄（CI 颜料黄 34）Lead sulfochromate yellow(C.I.Pigment Yellow 34)215-693-7 1344-37-2 致癌、致突变、致生殖毒性 CMR 涂料、颜料和塑料的着色剂 Used as colorant in painting,printing inks and plastic 27 铬酸铅 Lead chromate 231-846-0 7758-97-6 致癌、致突变、致生殖毒性 CMR 涂料、颜料、橡胶和塑料的着色剂 Used as colorant in painting,prin
19、ting inks,rubber and plastic 28 丙烯酰胺 Acrylamide（2010 年 3 月 30 日）201-173-7 79-06-1 致癌、致突变、致生殖毒性 CMR 合成聚丙烯酰胺:用于废水处理及纸张加工，作灌浆剂，用于纺织品加工。Synthesis of Polyacrylamide:for waste water treatment and paper processing,as a filling agent for textile processing.第三批第三批 SVHC 清单清单(2010 年年 6 月月 18 日公布，共日公布，共 8 种种)Th
20、e Third Batch of SVHC List(Published on June 18,2010,total 8)序号 NO.物质名称 Substance name EC 号 EC No CAS 号 CAS No 高关注属性 SVHC property 用途 Use 29 三氯乙烯 Trichloroethylene 201-167-4 79-01-6 致癌 Carcinogen 金属部件的清洁及脱脂；粘和剂中的溶剂；生产氯化和氟化有机化合物的介质。Metal parts cleaning and degreasing;binder in the solvent;production
21、of chlorinated and fluorinated organic compounds 序号 NO.物质名称 Substance name EC 号 EC No CAS 号 CAS No 高关注属性 SVHC property 用途 Use Media.30 硼酸 Boric acid 233-139-2 234-343-4 10043-35-3 11113-50-1 生殖毒性 Toxic for reproduction 用于：杀虫剂，防腐剂，个人护理产品，食品添加剂，玻璃，陶瓷，橡胶，化肥，阻燃剂，油漆，工业流体，制动液，焊接产品，冲印剂。For pesticides,prese
22、rvatives,personal care products,food additives,glass,ceramics,rubber,fertilizer,flame retardants,paints,industrial fluids,brake fluids,welding products,printing agent.31 无水四硼酸钠 Disodium tetraborate,anhydrous 215-540-4 1303-96-4 1330-43-4 12179-04-3 生殖毒性 Toxic for reproduction 用于：玻璃，玻璃纤维，陶瓷，清洁剂，个人护理产
23、品，工业流体，冶金术，粘接材料，阻燃剂，杀虫剂，化肥。For glass,glass fiber,ceramics,detergents,personal care products,industrial fluids,metallurgy,bonding materials,flame retardants,pesticides,fertilizers.32 水合硼酸钠 Tetraboron disodium heptaoxide,hydrate 235-541-3 12267-73-1 生殖毒性 Toxic for reproduction 33 铬酸钠 Sodium chromate 2
24、31-889-5 7775-11-3 致癌、致突变、致生殖毒性 CMR 实验室分析试剂，生产其它铬化合物。Laboratory analytical reagents,production of other chromium compounds.34 铬酸钾 Potassium chromate 232-140-5 7789-00-6 致癌、致基因突变 Carcinogen and mutagen 金属净化和涂层，生产试剂和化学品，生产纺织品，陶瓷染色剂，羽毛染色，制革及敷料，生产颜料及墨水，实验室分析试剂，烟火制造。Used as a corrosion inhibitor for trea
25、tment and coating of metals,for manufacture of reagents,chemicals and textiles,序号 NO.物质名称 Substance name EC 号 EC No CAS 号 CAS No 高关注属性 SVHC property 用途 Use as a colouring agent in ceramics,in the manufacture of pigments/inks and in the laboratory as analytical agent.35 重铬酸铵 Ammonium dichromate 232-1
26、43-1 2151163 致癌、致突变、致生殖毒性 CMR 氧化剂，实验室（分析试剂），鞣皮，生产纺织品，感光胶片的生产(阴极射线管)，金属处理 Mainly used as an oxidising agent.Other known uses are in the manufacture of photosensitive screens and as mordant in the manufacture of textiles.Minor uses seem to comprise metal treatment and laboratory analytical agent.36 重铬
27、酸钾 Potassium dichromate 231-906-6 7778-50-9 致癌、致突变、致生殖毒性 CMR 铬金属制造，腐蚀抑制剂，纺织品媒染剂，实验室分析剂，实验室玻璃器皿清洗，其他试剂生产和照片曝光氧化剂。Used for chrome metal manufacturing and as corrosion inhibitor for treatment and coating of metals.It is further used as textile mordant,as laboratory analytical agent,for cleaning of labo
28、ratory glassware,in the manufacture of other reagents and as oxidising agent in photolithography.第四批第四批 SVHC 清单清单(2010 年年 12 月月 15 日公布，共日公布，共 8 种种)The Four Batch of SVHC List(Published on December 15,2010,total 8)序号 NO.物质名称 Substance name EC 号 EC No CAS 号 CAS No 高关注属性 SVHC property 用途 Use 37 硫酸钴 Cob
29、alt(II)sulphate 233-334-2 10124-43-3 致癌和致生殖毒性 Carcinogenic and 用于陶瓷釉料和油漆催干剂，也用于电镀、碱性电池、生产含铬颜料和其它铬产品，还用于催化剂、分析试剂、饲料添加剂、序号 NO.物质名称 Substance name EC 号 EC No CAS 号 CAS No 高关注属性 SVHC property 用途 Use toxic to reproduction 轮胎胶黏剂 Used in ceramic glazes and paint driers,also used in electroplating,alkaline
30、batteries,the production of chromium chromium pigments and other products,but also for catalysts,reagents,feed additives,adhesives tires.38 硝酸钴 Cobalt(II)dinitrate 233-402-1 10141-05-6 致癌和致生殖毒性 Carcinogenic and toxic to reproduction 用于催化剂等其他化合物的生产，电池，表面处理，陶瓷工业 Mainly used in the manufacture of other
31、 chemicals including catalysts.Further applications may include surface treatment and in batteries.39 碳酸钴 Cobalt(II)carbonate 208-169-4 513-79-1 致癌和致生殖毒性 Carcinogenic and toxic to reproduction 用于生产催化剂，颜料、陶瓷、玻璃颜料、饲料，肥料。For the production of catalysts,pigments,ceramics,glass,paint,feed,fertilizer.40 醋
32、酸钴 Cobalt(II)diacetate 200-755-8 71-48-7 致癌和致生殖毒性 Carcinogenic and toxic to reproduction 主要用于磁性材料、电子元件材料、硬质合金材料、搪瓷、瓷釉、陶瓷、釉彩、玻璃、钴催化剂等。Mainly used for magnetic materials,electronic components materials,carbide materials,ceramic,enamel,ceramic,glaze,glass,cobalt catalyst.41 乙二醇单甲醚 2-Methoxyethanol 203-
33、713-7 109-86-4 致生殖毒性 Toxic to reproduction 溶剂，清漆的稀释剂，印染工业用作渗透剂和匀染剂，燃料工业用作添加剂，纺织工业用于染色助剂。Solvents,varnish thinners,printing and dyeing industry as a penetrant and leveling agent,used as an additive fuel industry,the textile industry for dyeing auxiliaries.序号 NO.物质名称 Substance name EC 号 EC No CAS 号 CA
34、S No 高关注属性 SVHC property 用途 Use 42 乙二醇单乙醚 2-Ethoxyethanol 203-804-1 110-80-5 致生殖毒性 Toxic to reproduction 用作溶剂，以及皮革着色剂、乳化剂、稳定剂、涂料稀释剂、脱漆剂、有机中间体等。Used as solvent,and the leather coloring agents,emulsifiers,stabilizers,paint thinner,paint remover,organic intermediates.43 三氧化铬 Chromium trioxide 215-607-8
35、 1333-82-0 致癌和致突变 Carcinogenic and mutagenic 用于电镀、制高纯金属铬、染料、合成橡胶及油脂精炼等，水中木料防腐剂的固色剂。Used in electroplating,production of high purity chromium,dyes,synthetic rubber and oil refining,water,wood preservatives fixative.44 三氧化二铬及其低聚物产生的酸 铬酸，二铬酸，铬酸及二铬酸的低聚物 Acids generated from chromium trioxide and their o
36、ligomers Group containing:Chromic acid,Dichromic acid,Oligomers of chromic acid and dichromic acid 231-801-5 236-881-5 7738-94-5 13530-68-2 致癌 Carcinogenic 用于金属表面处理，如电镀，软化膜，增亮剂。也作为水中使用的木料防腐剂的固色剂。还可能用作油漆，色粉，催化剂，洗涤剂的生产，以及用作氧化剂。For metal surface treatment,such as electroplating,softening film,brighteni
37、ng agent.Wood preservatives as a fixing agent.May also be used as paints,pigments,catalysts,detergent production,as well as oxidants.第五批第五批 SVHC 清单清单(2011 年年 6 月月 20 日公布，共日公布，共 7 种种)The Five Batch of SVHC List(Published on June 20,2011,total 7)序号 NO.物质名称 Substance name EC 号 EC No CAS 号 CAS No 高关注属性
38、SVHC property 用途 Use 45 乙二醇乙醚乙酸酯 2-ethoxyethyl acetate 203-839-2 111-15-9 生殖毒性 Toxic for reproduction 涂料、油漆中的溶剂；化工中间体；塑料和橡胶涂料。Paint,paint solvents;chemical intermediates;plastics and rubber coatings.46 铬酸锶 Strontium chromate 232-142-6 7789-6-2 致癌 Carcinogenic 电镀铬；颜料和金属缓蚀剂；PVC 着色剂，汽车涂层。Chrome plating
39、;pigments and metal corrosion inhibitor;PVC colorants,automotive coatings.47 邻苯二甲酸二(C7-11 支链与直链)烷基酯 1,2-Benzenedicarboxylic acid,di-C7-11-branched and linear alkyl esters(DHNUP)271-084-6 68515-42-4 致生殖毒性 Toxic for reproduction 塑料、密封剂和胶粘剂中的增塑剂。Plastics,sealants and adhesives plasticizer.48 肼 Hydrazin
40、e 206-114-9 302-01-2 7803-57-8 致癌 Carcinogenic 用于制造异烟肼、照相显影药剂、喷气式发动机燃料、火箭燃料、抗氧剂、还原剂、高压锅炉给水脱氧剂等。For the manufacture of isoniazid,photographic developing agents,jet fuel,rocket fuel,antioxidants,reducing agents,high-pressure boiler feed water deoxidation agent.49 N-甲基吡咯烷酮1-methyl-2-pyrrolidone 212-828
41、-1 872-50-4 致生殖毒性 Toxic for reproduction 用于高级润滑油精制、聚合物的合成、绝缘材料、农药、颜料及清洗剂等 For senior oil refining,synthetic polymers,insulation materials,pesticides,paints and cleaning agents.50 1,2,3-三氯丙烷 202-486-1 96-18-4 致癌及生殖毒性 生产有机氯溶剂的中间体；聚合物和橡胶生产中的交联剂;用于1,2,3-trichloropropane Carcinogenic&toxic for reproducti
42、on 清除油漆，清漆，以及去除油脂。Intermediate production of organic chlorine solvents;polymer and crosslinking agent in rubber production;for removal of paint,varnish,grease removal.51 邻苯二甲酸（C6-8 支链）烷基酯，富 C7（DIHP）1,2-Benzenedicarboxylic acid,di-C6-8-branched alkyl esters,C7-rich(DIHP)276-158-1 71888-89-6 致生殖毒性 Tox
43、ic for reproduction PVC,涂层，印刷油墨中的增塑剂。PVC,coatings,printing inks plasticizer.第六批第六批 SVHC 清单清单(2011 年年 12 月月 19 日公布，共日公布，共 20 种种)The Six Batch of SVHC List(Published on December 19,2011,total 20)序号 NO.物质名称 Substance name EC 号 EC No CAS 号 CAS No 高关注属性 SVHC property 用途 Use 52 铬酸铬 Dichromium tris(chromat
44、e)246-356-2 24613-89-6 致癌 Carcinogenic 主要用于航空/航空航天，钢铁和铝的涂料行业的金属表面处理的混合物。Mainly used in mixtures for metal surface treatment in the aeronautic/aerospace,steel and aluminium coating sectors.53 氢氧化铬酸锌钾 Potassium hydroxyoctaoxodizincatedi-chromate 234-329-8 11103-86-9 致癌 Carcinogenic 主要用于涂料，航空/航天，钢铁和铝卷材
45、涂料和汽车涂料行业。Mainly used in coatings in the aeronautic/aerospace,steel and aluminium coil coating and vehicle coating sectors.54 锌黄 Pentazinc chromate 256-418-0 49663-84-5 致癌 Carcinogenic 主要用于涂料，汽车涂料和航空/航天部门 Mainly used in coatings in the vehicle coating and aeronautic/序号 NO.物质名称 Substance name EC 号 EC
46、 No CAS 号 CAS No 高关注属性 SVHC property 用途 Use octahydroxide aerospace sectors.55 硅酸铝耐火陶瓷纤维 Aluminosilicate Refractory Ceramic Fibres(RCF)-致癌 Carcinogenic 耐火陶瓷纤维用于高温隔热，几乎完全是在工业应用（工业窑炉和设备，绝缘设备，汽车和飞机/航空航天产业），防火（建筑和工业加工设备）。Used for high-temperature insulation,almost exclusively in industrial applications(
47、insulation of industrial furnaces and equipment,equipment for the automotive and aircraft/aerospace industry)and in fire protection(buildings and industrial process equipment).56 氧化锆硅酸铝耐火陶瓷纤维 Zirconia Aluminosilicate Refractory Ceramic Fibres(Zr-RCF)-致癌 Carcinogenic 用于高温隔热，几乎完全是在工业应用（工业窑炉和设备，绝缘设备，汽车
48、和飞机/航空航天产业），防火（建筑和工业加工设备）。Used for high-temperature insulation,almost exclusively in industrial applications(insulation of industrial furnaces and equipment,equipment for the automotive and aircraft/aerospace industry)and in fire protection(buildings and industrial process equipment).57 甲醛与苯胺的低聚反应产物
49、 Formaldehyde,oligomeric reaction products with aniline(technical MDA)500-036-1 25214-70-4 致癌 Carcinogenic 主要用于制造其他物质。次要用途是作为固化剂，环氧树脂，例如卷，管道和模具，以及用于胶粘剂的生产。Mainly used for manufacture of other substances.Minor uses are as hardener for epoxy resins,e.g.for the production of rolls,pipes and moulds,and
50、as well for adhesives.序号 NO.物质名称 Substance name EC 号 EC No CAS 号 CAS No 高关注属性 SVHC property 用途 Use 58 邻苯二甲酸二甲氧乙酯(DMEP）Bis(2-methoxyethyl)phthalate 204-212-6 117-82-8 生殖毒性 Toxic for reproduction 主要用作乙酸纤维素的增塑剂，也用作气相色谱固定液、三乙酸片基的增感剂和溶剂。Cellulose acetate is mainly used as plasticizers,are also used as ga