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1、氢氧化钠溶液安全技术说明书 resource-processing enterprises the proportion of production value of industrial output reached.%.High-tech industrial output value accounts for only.%,below the city-wide average.A percentage point,and.Of a percentage point.Level of industrial development,backbone enterprises grow,tot
2、al investment in strategic industries and the growth rate of these indicators in all.Rankings are relatively backward.At present,the increasingly serious situation of energy saving and emission reduction,new normal required should focus more on the quality and efficiency of economic development.Impr
3、ovement of quality and efficiency must rely on advanced technology and talents into the lead.Three is to implement three is the main driving force for accelerating urbanization.Urbanization is an important characteristic of urban population growth,urban expansion,improve the quality of peoples lives
4、.Realization of these factors,need to attract good as the carrier of the project,provide jobs for more people,make towns more attractive,promote economic development throughout the region.Only by vigorously promoting three,we can attract more projects,more enterprises,for the town to build a solid f
5、oundation,to provide an inexhaustible power.Four is the implementation of three is the top priority of every town,street,Department.Three as the Countys first project,core work,each town must seize,grasp the reality of the street.At present,the County also fully take into account the practical diffi
6、culties exist in villages and towns,determined by the wages of 氢氧化钠溶液安全技术说明书 第一部分 化学品及企业标识 化学品中文名:30%氢氧化钠溶液 化学品俗名或商品名:30%液碱 化学品英文名:Sodium hydroxide;Caustic soda 技术说明书编码:TTSX003 第二部分 成分/组分信息 纯品?混合物 化学品名称:氢氧化钠溶液 有害成分 浓度 CAS No.氢氧化钠 30%1310-73-2 第三部分 危险性概述 危险性类别:第 8.2 类 碱性腐蚀品 侵入途径:吸入、食入 健康危害:本品有强烈刺激和腐蚀
7、性。腐蚀鼻中隔;直接接触皮肤和 眼可引起灼伤;误服可造成消化道灼伤，粘膜糜烂、出血和休克。环境危害:对水体可造成污染。燃爆危险:本品不燃，具强腐蚀性、强刺激性，可致人体灼伤。第四部分 急救措施 皮肤接触:立即脱去污染的衣着，用大量流动清水冲洗至少 15 分钟 就医。眼睛接触:立即提起眼睑，用大量就动清水或生理盐水彻底冲洗至少 15 分钟。就医。吸入:迅速脱离现场至空气新鲜处。保持呼吸道通畅。如呼吸困难，给输氧。如呼吸停止，立即进行人工呼吸。就医。食入:用水漱口，给饮牛奶或蛋清。就医。resource-processing enterprises the proportion of produc
8、tion value of industrial output reached.%.High-tech industrial output value accounts for only.%,below the city-wide average.A percentage point,and.Of a percentage point.Level of industrial development,backbone enterprises grow,total investment in strategic industries and the growth rate of these ind
9、icators in all.Rankings are relatively backward.At present,the increasingly serious situation of energy saving and emission reduction,new normal required should focus more on the quality and efficiency of economic development.Improvement of quality and efficiency must rely on advanced technology and
10、 talents into the lead.Three is to implement three is the main driving force for accelerating urbanization.Urbanization is an important characteristic of urban population growth,urban expansion,improve the quality of peoples lives.Realization of these factors,need to attract good as the carrier of t
11、he project,provide jobs for more people,make towns more attractive,promote economic development throughout the region.Only by vigorously promoting three,we can attract more projects,more enterprises,for the town to build a solid foundation,to provide an inexhaustible power.Four is the implementation
12、 of three is the top priority of every town,street,Department.Three as the Countys first project,core work,each town must seize,grasp the reality of the street.At present,the County also fully take into account the practical difficulties exist in villages and towns,determined by the wages of resourc
13、e-processing enterprises the proportion of production value of industrial output reached.%.High-tech industrial output value accounts for only.%,below the city-wide average.A percentage point,and.Of a percentage point.Level of industrial development,backbone enterprises grow,total investment in stra
14、tegic industries and the growth rate of these indicators in all.Rankings are relatively backward.At present,the increasingly serious situation of energy saving and emission reduction,new normal required should focus more on the quality and efficiency of economic development.Improvement of quality an
15、d efficiency must rely on advanced technology and talents into the lead.Three is to implement three is the main driving force for accelerating urbanization.Urbanization is an important characteristic of urban population growth,urban expansion,improve the quality of peoples lives.Realization of these
16、 factors,need to attract good as the carrier of the project,provide jobs for more people,make towns more attractive,promote economic development throughout the region.Only by vigorously promoting three,we can attract more projects,more enterprises,for the town to build a solid foundation,to provide
17、an inexhaustible power.Four is the implementation of three is the top priority of every town,street,Department.Three as the Countys first project,core work,each town must seize,grasp the reality of the street.At present,the County also fully take into account the practical difficulties exist in vill
18、ages and towns,determined by the wages of 第五部分 消防措施 危险特性:与酸发生中和反应并放热。具有强腐蚀性。有害燃烧产物:可能产生有害的毒性烟雾。灭火方法及灭火剂:本品不燃，由其它物质引起火灾时，应注意该物质的腐蚀性。灭火注意事项:消防人员应穿防酸碱消防服。第六部分 泄漏应急处理 应急处理:隔离泄漏污染区，限制出入。液碱泄漏:收集回收后用水冲洗，冲洗水经中和 处理后排入废系统。消除方法:加入大量水中，调节至中性，再放入废水系统。也可用大量水冲洗，经稀释的洗 水放入废水系统。如大量泄漏，收集回收或无害处理后废弃。第七部分 操作处理与储存 操作注意事项:
19、操作人员必须经过专门培训持证上岗，严格遵守 工艺规程和岗位操作法。操作人员穿耐酸碱服，戴耐酸碱手套，戴防护眼镜。避免与酸类接触。搬运时要轻装轻卸，防止包装及 容器损坏。配备泄漏应急处理设备。应当注意倒空容器内的残留 物。稀释或制备溶液时，应把碱加入水中，避免沸腾和飞溅。储存注意事项:液碱贮槽应设围堤，并有明显标志。第八部分 暴露控制/个体防护 3 最高容许浓度:中国 MAC(mg/m):0.5 3 前苏联 MAC(mg/m):0.5 3 美国 TLVTWA:OSHA 2 mg/m 3 美国 TLVSTEL:ACGIH 2mg/m 监测方法:重量法 工程控制:密闭操作。提供安全淋浴和洗眼设备。呼
20、吸系统防护:穿耐酸碱服，戴耐酸碱手套，戴防护眼镜。必要时，佩戴空气(氧气)呼吸 器。眼睛防护:呼吸系统防护中已作防护或佩戴防护眼镜。身体防护:穿耐酸碱服。County financial is responsible for the allocation of the town street,that decided to solve the street,the towns worries.This requires each town street to focus more on attracting more,according to the characteristics of th
21、eir respective jurisdictions to examine how good business to ensure that large projects,projects.The meeting,to the relevant Department,the unit issued investment tasks and develop the assessment methods,to look after,ensure to complete the task.(B)the precise grasping the three directions.The 18 se
22、ssion of the plenary session of the party established the innovation,coordination,development of green,open,shared five concepts,This is our grasp three the General principles of the work.We on both projects,technology and talent,to be compared with great ideas,never to be not up to the safety stand
23、ards,environmental protection and energy saving and emission reduction projects.One is to accurately attract location.My County is located in the yimeng mountain,dredging the river originated,the most valuable asset is the side of the mountains,the biggest advantages is the side of the mountains.Mai
24、ntaining a good ecological environment is a prerequisite for development,especially the environmental protection requirements under extremely strict conditions,pollution items on we must not.As chemicals,tires,metal smelting and resource-processing enterprises the proportion of production value of i
25、ndustrial output reached.%.High-tech industrial output value accounts for only.%,below the city-wide average.A percentage point,and.Of a percentage point.Level of industrial development,backbone enterprises grow,total investment in strategic industries and the growth rate of these indicators in all.
26、Rankings are relatively backward.At present,the increasingly serious situation of energy saving and emission reduction,new normal required should focus more on the quality and efficiency of economic development.Improvement of quality and efficiency must rely on advanced technology and talents into t
27、he lead.Three is to implement three is the main driving force for accelerating urbanization.Urbanization is an important characteristic of urban population growth,urban expansion,improve the quality of peoples lives.Realization of these factors,need to attract good as the carrier of the project,prov
28、ide jobs for more people,make towns more attractive,promote economic development throughout the region.Only by vigorously promoting three,we can attract more projects,more enterprises,for the town to build a solid foundation,to provide an inexhaustible power.Four is the implementation of three is th
29、e top priority of every town,street,Department.Three as the Countys first project,core work,each town must seize,grasp the reality of the street.At present,the County also fully take into account the practical difficulties exist in villages and towns,determined by the wages of 手防护:戴耐酸碱手套。其它防护:工作场所禁止
30、吸烟、进食和饮水、饭前要洗手。工作完毕，淋浴更衣。注意个人 清洁卫生。第九部分 理化特性 外观与性状:常温下为无色粘稠状液体，由于杂质含量的不同呈微黄 透明。PH 值:氢氧化钠溶液为强碱 PH 值大于 14 熔点(?):318.4 液碱相对密度(水=1):浓度 30%50%时为 1.32971.5253(20?)沸点(?):1390 相对蒸汽密度:无资料 饱和蒸汽压(kpa):0.13/739?燃烧热:无意义 临界温度:无资料 临界压力:无资料 辛醇/水分配系数:无资料 闪点(?):无意义 爆炸上限,(V/V):无意义 爆炸下限,(V/V):无意义 引燃温度(?):无意义 溶解性:易溶于水、乙
31、醇、甘油、不溶于丙酮。主要用途:用于肥皂工业、石油精炼、造纸、人造丝、染色、制革、医药、有机合成等。第十部分 稳定性和反应活性 稳定性:稳定 禁忌物:强酸、易燃或可燃物、二氧化碳、过氧化物、水。避免接触的条件:潮湿空气(指固碱)聚合危害:不能出现 分解产物:可能产生有害的毒性烟雾。resource-processing enterprises the proportion of production value of industrial output reached.%.High-tech industrial output value accounts for only.%,below t
32、he city-wide average.A percentage point,and.Of a percentage point.Level of industrial development,backbone enterprises grow,total investment in strategic industries and the growth rate of these indicators in all.Rankings are relatively backward.At present,the increasingly serious situation of energy
33、 saving and emission reduction,new normal required should focus more on the quality and efficiency of economic development.Improvement of quality and efficiency must rely on advanced technology and talents into the lead.Three is to implement three is the main driving force for accelerating urbanizat
34、ion.Urbanization is an important characteristic of urban population growth,urban expansion,improve the quality of peoples lives.Realization of these factors,need to attract good as the carrier of the project,provide jobs for more people,make towns more attractive,promote economic development through
35、out the region.Only by vigorously promoting three,we can attract more projects,more enterprises,for the town to build a solid foundation,to provide an inexhaustible power.Four is the implementation of three is the top priority of every town,street,Department.Three as the Countys first project,core w
36、ork,each town must seize,grasp the reality of the street.At present,the County also fully take into account the practical difficulties exist in villages and towns,determined by the wages of resource-processing enterprises the proportion of production value of industrial output reached.%.High-tech in
37、dustrial output value accounts for only.%,below the city-wide average.A percentage point,and.Of a percentage point.Level of industrial development,backbone enterprises grow,total investment in strategic industries and the growth rate of these indicators in all.Rankings are relatively backward.At pre
38、sent,the increasingly serious situation of energy saving and emission reduction,new normal required should focus more on the quality and efficiency of economic development.Improvement of quality and efficiency must rely on advanced technology and talents into the lead.Three is to implement three is
39、the main driving force for accelerating urbanization.Urbanization is an important characteristic of urban population growth,urban expansion,improve the quality of peoples lives.Realization of these factors,need to attract good as the carrier of the project,provide jobs for more people,make towns mor
40、e attractive,promote economic development throughout the region.Only by vigorously promoting three,we can attract more projects,more enterprises,for the town to build a solid foundation,to provide an inexhaustible power.Four is the implementation of three is the top priority of every town,street,Dep
41、artment.Three as the Countys first project,core work,each town must seize,grasp the reality of the street.At present,the County also fully take into account the practical difficulties exist in villages and towns,determined by the wages of 第十一部分 毒理学资料 急性毒性:LD:无资料 50 LC:无资料 50 刺激性:家兔经眼:1%重度刺激;家兔经皮:50m
42、g/24 小时，重度刺 激。第十二部分 生态学资料 生态毒性:由于呈强碱性，对水体可造成污染，对植物和水生生物应 给与特别注意。生物降解性:无资料 非生物降解性:无资料 第十三部分 废弃处置 废弃物性质:?危险废物 工业固体废物 废弃处置方法:处置前应参阅国家和地方有关法规。中和、稀释后，排入废水系统。废弃注意事项:操作者应穿防酸碱工作服，佩戴防护眼镜及耐酸碱手套。第十四部分 运输信息 危险货物编号:82001 UN 编号:1824 包装标志:腐蚀品 包装类别:?类 包装方法:液碱采用槽车或贮槽，槽车有“腐蚀性物品”的标志。运输注意事项:运输过程中要确保容器不泄漏，不倒塌、不坠落、不 损坏。严
43、禁与易燃物或可燃物、酸类、食用化学品等混装混运。运输时运输车应配备泄漏应急处理设备。第十五部分 法规信息 法规信息:危险化学品安全管理条例(国务院令第 344 号)危险货物名表(GB122682005)County financial is responsible for the allocation of the town street,that decided to solve the street,the towns worries.This requires each town street to focus more on attracting more,according to t
44、he characteristics of their respective jurisdictions to examine how good business to ensure that large projects,projects.The meeting,to the relevant Department,the unit issued investment tasks and develop the assessment methods,to look after,ensure to complete the task.(B)the precise grasping the th
45、ree directions.The 18 session of the plenary session of the party established the innovation,coordination,development of green,open,shared five concepts,This is our grasp three the General principles of the work.We on both projects,technology and talent,to be compared with great ideas,never to be no
46、t up to the safety standards,environmental protection and energy saving and emission reduction projects.One is to accurately attract location.My County is located in the yimeng mountain,dredging the river originated,the most valuable asset is the side of the mountains,the biggest advantages is the s
47、ide of the mountains.Maintaining a good ecological environment is a prerequisite for development,especially the environmental protection requirements under extremely strict conditions,pollution items on we must not.As chemicals,tires,metal smelting and resource-processing enterprises the proportion
48、of production value of industrial output reached.%.High-tech industrial output value accounts for only.%,below the city-wide average.A percentage point,and.Of a percentage point.Level of industrial development,backbone enterprises grow,total investment in strategic industries and the growth rate of
49、these indicators in all.Rankings are relatively backward.At present,the increasingly serious situation of energy saving and emission reduction,new normal required should focus more on the quality and efficiency of economic development.Improvement of quality and efficiency must rely on advanced techn
50、ology and talents into the lead.Three is to implement three is the main driving force for accelerating urbanization.Urbanization is an important characteristic of urban population growth,urban expansion,improve the quality of peoples lives.Realization of these factors,need to attract good as the car