2022年2022高中化学3.1《从铝土矿到铝合金》规律总结苏教版必修1 .pdf

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1、规律总结规律一:氢氧化铝的两性氢氧化铝的两性一直是高考热点之一,其原因在于它的典型性,相关的反应可用下式表示:A1O2A(OH)3A3由于氢氧化铝既可溶于强碱又可溶于强酸,所以制备氢氧化铝宜采用以下途径:铝盐与氨水的反应:A33NH3H2OA(OH)3 3NH4偏铝酸盐与碳酸的反应:AO2CO22H2OA(OH)3 NaHCO3 A3与 AO2在溶液中的双水解反应:A33AO2 6H2O4A(OH)3规律二:A与 NaOH溶液反应的电子转移表示方法A与 NaOH溶液反应,首先是A与水电离出的H发生氧化还原反应:生成的 A(OH)3随即与 NaOH发生复分解反应:A(OH)3NaOHNaAO22

2、H2O 以上反应综合起来可表示为在反应中只有水电离出的H能接受 A给出的电子,NaOH 及水电离的OH本身带负电不能接受电子,若不需表示电子转移,则只需写成:2A2H2O 2NaOHNaAO23H2规律三:氢氧化铝沉淀的图象分析氢氧化铝沉淀图象大致可分为以下8 类 主要围绕A1(OH)3沉淀的生成和溶解展开研究:向 AC3溶液中滴加NaOH 溶液直至过量(图34):AB AC33NaOHA(OH)3 3NaC BC NaOH A(OH)3NaAO22H2O 图 34 向盐酸酸化后的AC3溶液滴加NaOH 溶液直至过量(35):AB HC NaOHNaC H2O BC AC33NaOHA(OH)

3、3 3NaC CD NaOH A(OH)3NaAO22H2O 图 35 向 NaAO2溶液滴加HC至过量(图36):AB:NaA1O2HC H2ONaC A(OH)3BC:A(OH)33HCAC33H2O 图 36 向 NaOH 与 NaAO2混合液中滴加HC直至过量(图37):AB HC NaOHNaC H2O BC 同 A B CD 同 B C 图 37 向 NaOH 溶液滴加AC3,直至过量(图3 8):AB 4NaOH AC3NaAO23NaC 2H2O(12NaOH 3AC33NaAO29NaC 6H2O)文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z

4、8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W

5、1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10

6、A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z

7、8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W

8、1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10

9、A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z

10、8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W

11、1L10Z2 ZY10W10Z8E1Z10BC 3NaAO2AC36H2O4A(OH)3 3NaC 图 38 向盐酸中滴加NaAO2溶液直至过量(图39)AB 4HC NaAO2AC3NaC H2O BC AC33NaAO26H2O4A(OH)3 3NaC 图 39 图 310 向等物质的量混合的MgC2、AC3溶液中滴加NaOH 直至过量(图311):AB MgC22NaOHMg(OH)2 2NaC AC33NaOHA(OH)3 3NaC BC A(OH)3NaOHNaAO22H2O 图 311 文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编

12、码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY

13、10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5

14、HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编

15、码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY

16、10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5

17、HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编

18、码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY

19、10W10Z8E1Z10规律四:产生A(OH)3沉淀的定量规律(1)强碱与A3反应的定量规律(2)强酸与AO2反应的定量规律:(3)A3与 AO2两种盐溶液反应的定量规律:A33AO2 6H2O4A(OH)3思维过程一、氧化铝(A2O3)氧化铝是白色的难熔物质,较好的耐火材料。典型的两性氧化物:A2O36H2A33H2O;A2O32OH2AO2H2O(思考具体的化学反应并写出化学方程式)电解制备铝单质:2A2O34A3O2(思考冰晶石的作用)二、氢氧化铝A(OH)31氢氧化铝 A(OH)3制备(1)铝盐与氨水的反应:A33NH3H2OA(OH)3 3NH4(不可用强碱)(2)偏铝酸盐与碳酸的反

20、应:AO2CO2 2H2OA(OH)3 HCO3(不可用强酸)。(3)A3与 AO2在溶液中的双水解反应:A33AO26H2O4A(OH)32氢氧化铝 A(OH)3的物质白色的絮状沉淀(溶液中)具有很强的吸附能力,是很好的净水剂。典型的两性氢氧化物:A(OH)33HA3 3H2O A(OH)3OHAO22H2O 文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO1

21、0A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10

22、Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9

23、W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO1

24、0A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10

25、Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9

26、W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO1

27、0A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10(思考具体的化学反应并写出化学反应方程式)受热分解:2A(OH)3A2O3 3H2O 三、硫酸铝钾KA(SO4)2十二水硫酸铝钾KA(SO4)212H2俗名是明矾KA

28、(SO4)2KA32SO24;A33H2OA(OH)3(胶状)3H(铝离子水解;可逆反应)四、铝单质的性质1活泼金属单质的通性(1)与非金属单质(氧气、氯气、硫等)的反应:4A3O22A2O3;2A3C22AC3;2A3SA2S3(2)与水的反应(高温条件且反应缓慢):2A6H2O2A(OH)33H2(3)与酸的反应:2A6HC2AC33H2(4)与盐溶液的反应:2A3CuSO4A2(SO4)33Cu 2特性(1)与强碱溶液的反应:2A2NaOH 2H2O2NaAO23H2(2)常温下遇浓硫酸、浓硝酸钝化(3)铝热反应:2AFe2O32FeA2O3;2ACr2O32CrA2O3 文档编码:CO

29、10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W1

30、0Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B

31、9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO

32、10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W1

33、0Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B

34、9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO

35、10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10文档编码:CO10A3T3H4Y5 HN2B9W1L10Z2 ZY10W10Z8E1Z10

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