大学有机化学习题及答案.pdf

《大学有机化学习题及答案.pdf》由会员分享，可在线阅读，更多相关《大学有机化学习题及答案.pdf（5页珍藏版）》请在taowenge.com淘文阁网|工程机械CAD图纸|机械工程制图|CAD装配图下载|SolidWorks_CaTia_CAD_UG_PROE_设计图分享下载上搜索。

1、可编辑 word,供参考版！第一章绪论1.1 扼要归纳典型的以离子键形成的化合物与以共价键形成的化合物的物理性质。答案：离子键化合物共价键化合物熔沸点高低溶解度溶于强极性溶剂溶于弱或非极性溶剂硬度高低1.2NaCl 与 KBr 各 1mol 溶于水中所得的溶液与NaBr 及 KCl 各 1mol 溶于水中所得溶液是否相同？如将CH4 及 CCl4各 1mol 混在一起，与 CHCl3及 CH3Cl 各 1mol 的混合物是否相同？为什么？答案：NaCl 与 KBr 各 1mol 与 NaBr 及 KCl 各 1mol 溶于水中所得溶液相同。因为两者溶液中均为Na+,K+,Br,Cl离子各 1m

2、ol。由于 CH4 与 CCl4及 CHCl3与 CH3Cl 在水中是以分子状态存在，所以是两组不同的混合物。1.3 碳原子核外及氢原子核外各有几个电子？它们是怎样分布的？画出它们的轨道形状。当四个氢原子与一个碳原子结合成甲烷（CH4）时，碳原子核外有几个电子是用来与氢成键的？画出它们的轨道形状及甲烷分子的形状。答案：C+624H+11CCH4中 C中有 4个电子与氢成键为 SP3杂化轨道,正四面体结构CH4SP3杂化HHHHC1s 2s 2p 2p2pyzx2pyxyz2pzxyz2pxxyz2sH1.4 写出下列化合物的Lewis 电子式。a.C2H2 b.CH3Cl c.NH3d.H2S

3、 e.HNO3f.HCHO g.H3PO4h.C2H6 i.C2H2 j.H2SO4 答案：a.CCHHHHCCHHHH或b.HCHHClc.HNHHd.HSHe.HONOOf.OCHHg.OPOOOHHHh.HCCHHHHHOPOOOHHH或可编辑 word,供参考版！i.HCCHj.OSOHHOOOSOOOHH或1.5 下列各化合物哪个有偶极矩？画出其方向。a.I2b.CH2Cl2c.HBr d.CHCl3e.CH3OH f.CH3OCH3答案：b.ClCClHHc.HBrd.HCClClCle.H3COHH3COCH3f.1.6根据 S 与 O 的电负性差别，H2O 与 H2S相比，哪个

4、有较强的偶极-偶极作用力或氢键？答案：电负性O S,H2O 与 H2S 相比，H2O 有较强的偶极作用及氢键。第二章饱和脂肪烃2.2 用系统命名法（如果可能的话，同时用普通命名法）命名下列化合物，并指出(c)和(d)中各碳原子的级数。a.CH3(CH2)3CH(CH2)3CH3C(CH3)2CH2CH(CH3)2b.CHHCHHCHHHCHHCHHCHHHc.CH3CH2C(CH2CH3)2CH2CH3d.CH3CH2CHCH2CH3CHCHCH2CH2CH3CH3CH3e.CCH3H3CCH3Hf.(CH3)4Cg.CH3CHCH2CH3C2H5h.(CH3)2CHCH2CH2CH(C2H5

5、)2124。答案：a.2,4,4三甲基正丁基壬烷 butyl 2,4,4 trimethylnonane b.正己烷hexane c.3,3二乙基戊烷3,3diethylpentane d.3甲基异丙 基 辛 烷 isopropyl 3 methyloctane e.甲 基 丙 烷（异 丁 烷）methylpropane(iso-butane)f.2,2二甲基丙烷（新戊烷）2,2dimethylpropane(neopentane)g.3甲基戊烷 methylpentane h.甲基乙基庚烷5ethyl2methylheptane 2.3 下列各结构式共代表几种化合物？用系统命名法命名。a.C

6、H3CHCH3CH2CHCH3CHCH3CH3b.CH3CHCH3CH2CHCH3CHCH3CH3c.CH3CHCH3CHCH3CHCH3CHCH3CH3d.CH3CHCH2CHCH3CH3CHH3CCH3e.CH3CHCHCH2CHCH3CH3CH3CH3f.CH3CHCH3CHCHCH3CH3CHCH3CH3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4

7、H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7

8、A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:

9、CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 H

10、K4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 Z

11、L7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编

12、码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1

13、 HK4H1T10T2O8 ZL7A2P5Z1P3可编辑 word,供参考版！答案：a=b=d=e 为 2,3,5三甲基己烷c=f 为 2,3,4,5四甲基己烷写出下列各化合物的结构式，假如某个名称违反系统命名原则，予以更正。a.3,3二甲基丁烷b.2,4二甲基 5异丙基壬烷c.2,4,5,5四甲基4乙基庚烷d.3,4二甲基5乙基癸烷e.2,2,3三甲基戊烷f.2,3二甲基 2乙基丁烷g.2异丙基 4甲基己烷h.4乙基5,5 二甲基辛烷答案：a.错，应为2,2二甲基丁烷Cb.c.d.e.f.错，应为2,3,3 三甲基戊烷错，应为2,3,5三甲基庚烷g.h.2.9 将下列化合物按沸点由高到低排列

14、（不要查表）。a.3,3二甲基戊烷b.正庚烷c.2甲基庚烷d.正戊烷e.2甲基己烷答案：c b e a d 写出 2,2,4三甲基戊烷进行氯代反应可能得到的一氯代产物的结构式。答案：3 种123ClClCl2.12 下列哪一对化合物是等同的？（假定碳-碳单键可以自由旋转。）a.HBrBrHCH3CH3CH3HHCH3BrBrb.HBrHCH3BrCH3HCH3BrH3CBrH答案：a 是共同的用纽曼投影式画出1,2二溴乙烷的几个有代表性的构象。下列势能图中的A,B,C,D 各代表哪一种构象的内能？答案：BrHHBrHHABHHBrBrHHCBrHHHBrHDBrHHBrHH2.15 分子式为C

15、8H8的烷烃与氯在紫外光照射下反应，产物中的一氯代烷只有一种，写出文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H

16、1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A

17、2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:C

18、D4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK

19、4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL

20、7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码

21、:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3可编辑 word,供参考版！这个烷烃的结构。答案：这个化合物为2.16 将下列游离基按稳定性由大到小排列：a.CH3CH2CH2CHCH3CH3CH2CH2CH2CH2b.c.CH3CH2CCH3C

22、H3答案：稳定性c a b 第三章 不饱和脂肪烃3.1 用系统命名法命名下列化合物a.b.c.(CH3CH2)2C=CH2CH3CH2CH2CCH2(CH2)2CH3CH2CH3C=CHCHCH2CH3C2H5CH3d.(CH3)2CHCH2CH=C(CH3)2答案：a.2乙基丁烯 ethyl1 butene b.2丙基己烯propyl1hexene c.3,5二甲基庚烯3,5dimethyl 3heptene d.2,5二甲基己烯2,5dimethyl 2hexene 写出下列化合物的结构式或构型式，如命名有误，予以更正。a.2,4二甲基 2戊烯b.3丁烯c.3,3,5三甲基 1庚烯d.2乙

23、基 1戊烯e.异丁烯f.3,4二甲基 4戊烯g.反3,4二甲基 3己烯h.2甲基 3丙基 2戊烯答案：a.b.错，应为 1丁烯c.d.e.f.错，应为 2,3 二甲基戊烯g.h.错，应为 2甲基 3乙基己烯3.8 下列烯烃哪个有顺、反异构？写出顺、反异构体的构型，并命名。a.b.c.d.CH2=C(Cl)CH3C2H5CH=CHCH2ICH3CH=CHCH(CH3)2CH3CH=CHCH=CH2CH3CH=CHCH=CHC2H5CH3CH2C=CCH2CH3CH3C2H5e.f.答案：c,d,e,f 有顺反异构文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文

24、档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9

25、H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2

26、O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P

27、3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1

28、D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10

29、T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z

30、1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3可编辑 word,供参考版！c.C2H5CHCCH2IH(Z)1碘 2戊烯(E)1碘 2戊烯CC2H5CCH2IHHd.CHCCH(CH3)2H(Z)4甲基 2戊烯H3CCHCHCH(CH3)2H3C(E)4甲基 2戊烯e.CH3CCHCH(Z)1,3戊二烯HCH2CHCHCH(E)1,3 戊二烯H3CCH2f.CH3CCHC(2Z,4Z)2,4

31、 庚二烯HCHHC2H5CH3CCHCHCHC2H5H(2Z,4E)2,4庚二烯CHCHCH3CCHC2H5H(2E,4E)2,4庚二烯CHCHC(2E,4Z)2,4庚二烯H3CCHHC2H53.11 完成下列反应式，写出产物或所需试剂a.CH3CH2CH=CH2H2SO4b.(CH3)2C=CHCH3HBrc.CH3CH2CH=CH2CH3CH2CH2CH2OHd.CH3CH2CH=CH2CH3CH2CH-CH3OHe.(CH3)2C=CHCH2CH3O3ZnH2O,f.CH2=CHCH2OHClCH2CH-CH2OHOH答案：a.CH3CH2CH=CH2H2SO4CH3CH2CHCH3OS

32、O2OHb.(CH3)2C=CHCH3HBr(CH3)2C-CH2CH3Brc.CH3CH2CH=CH2BH3H2O2OHCH3CH2CH2CH2OHd.CH3CH2CH=CH2H2O/H+CH3CH2CH-CH3OHe.(CH3)2C=CHCH2CH3O3ZnH2O,CH3COCH3+CH3CH2CHOf.CH2=CHCH2OHCl2/H2OClCH2CH-CH2OHOH1).2).1).2).3.12 两瓶没有标签的无色液体，一瓶是正己烷，另一瓶是1己烯，用什么简单方法可以给它们贴上正确的标签？答案：1己烯正己烷Br2/CCl4or KMnO4无反应褪色正己烷1己烯文档编码:CD4N8P1

33、D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10

34、T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z

35、1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8

36、P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T

37、10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P

38、5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3文档编码:CD4N8P1D9H1 HK4H1T10T2O8 ZL7A2P5Z1P3