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1、2014 年普通高等学校招生全国统一考试（新课标卷）理科综合试卷化学7下列过程没有发生化学反应的是（）A用活性炭去除冰箱中的异味B用热碱水清除炊具上残留的油污C用浸泡过高锰酸钾溶液的硅藻土保鲜水果D用含硅胶、铁粉的透气小袋与食品一起密封包装8四联苯的一氯代物有（）A3 种B4 种C5 种D6 种9下列反应中，反应后固体物质增重的是（）A氢气通过灼热的CuO 粉末B二氧化碳通过Na2O2粉末C铝与 Fe2O3发生铝热反应D将锌粒投入Cu(NO3)2溶液10下列图示实验正确的是（）A除去粗盐溶液中的不溶物B碳酸氢钠受热分解C除去 CO 气体中的CO2 气体 D乙酸乙酯制备演示实验11一定温度下，下
2、列溶液的离子浓度关系式正确的是（）ApH=5 的 H2S溶液中，c(H+)=c(HS-)=1 10-5mol?L-1BpH=a 的氨水溶液，稀释10 倍后，其pH=b，则 a=b+1 CpH=2 的 H2C2O4 溶液与 pH=12 的 NaOH 溶液任意比例混合:c(Na+)+c(H+)=c(OH-)+c(HC2O4-)DpH 相同的 CH3COONaNaHCO3NaClO 三种溶液的c(Na+):12 2013 年 3 月我国科学家报道了如图所示的水溶液锂离子电池体系，下列叙述错误的是（）Aa 为电池的正极B电池充电反应为LiMn2O4=Li1-xMn2Ox+xLi C放电时，a极锂的化合
3、价发生变化D放电时，溶液中Li+从 b 向 a迁移13室温下，将 1mol 的 CuSO4?5H2O（s）溶于水会使溶液温度降低，热效应为 H1，将 1mol的 CuSO4(s)溶于水会使溶液温度升高，热效应为 H2，CuSO4?5H2O 受热分解的化学方程式为：CuSO4?5H2O(s)=CuSO4(s)+5H2O(l),热效应为 H3。则下列判断正确的是（）A H2H3 B H1H326（13 分）在容积为1.00L 的容器中，通入一定量的N2O4，发生反应N2O4(g)2NO2(g)，随温度升高，混合气体的颜色变深。回答下列问题：（1）反应的 H0（填“大于”“小于”）；100时，体系中
4、各物质浓度随时间变化如上图所示。在 060s 时段，反应速率v(N2O4)为 mol?L-1?s-1反应的平衡常数K1为。（2）100时达到平衡后，改变反应温度为T，c(N2O4)以 0.0020 mol?L-1?s-1的平均速率降低，经 10s 又达到平衡。T 100（填“大于”“小于”），判断理由是。列式计算温度T 是反应的平衡常数K2（3）温度 T 时反应达平衡后，将反应容器的容积减少一半，平衡向（填“正反应”或“逆反应”）方向移动，判断理由是。27（15 分）铅及其化合物可用于蓄电池，耐酸设备及X 射线防护材料等。回答下列问题：（1）铅是碳的同族元素，比碳多4 个电子层，铅在周期表的位
5、置为周期，第族：PbO2的酸性比 CO2的酸性（填“强”或“弱”）。（2）PbO2与浓盐酸共热生成黄绿色气体，反应的化学方程式为。（3）PbO2可由 PbO 与次氯酸钠溶液反应制得，反应的离子方程式为：PbO2也可以通过石墨为电极，Pb(NO3)2和 Cu(NO3)2的混合溶液为电解液电解制取。阳极发生的电极反应式，阴极观察到的现象是：若电解液中不加入Cu(NO3)2，阴极发生的电极反应式，这样做的主文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K
6、5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9
7、 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文
8、档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N1
9、0K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7
10、X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P
11、6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9
12、N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6文档编码:CH9B6U9N10K5 HF6H2O1X7X9 ZO4Q9S5E2P6要缺点是。（4）PbO2在加热过程发生分解的失重曲线如下图所示，已知失重曲线上的a 点为样品失重4.0%（-100%a样品起始质量点固体质量样品起始质量）的残留固体，若 a 点固体表示为PbO2或 mPbO2 nPbO2，列式计算x 值和 m:n 值。28（15 分）某小组以CoCl2 6H2O、过氧化氢、液氨、氯化铵固体为原料，在活性炭催化下，合成了橙黄色晶体X。为确定其组成，进行如下实验：氨的测定：精确称取w g X，加适量水溶解，注入如图所示的三颈瓶
13、中，然后逐滴加入足量 10%NaOH 溶液，通入水蒸气，将样品溶液中的氨全部蒸出，用V1 ml c1 mol L-1的盐酸溶液吸收。蒸氨结束后取下接收瓶，用c2mol L-1 NaOH 标准溶液滴定过剩的HCl，到终点时消耗 V2 mlNaOH 溶液。1.水2.安全管3.10%NaOH 溶液4.样品液5.盐酸标准溶液6.冰盐水1264A35BC氨的测定装置（已省略加热和夹持装置）氯的测定：准确称取样品X 配成溶液后用AgNO3标准溶液滴定，K2CrO4溶液为指示剂，至出现砖红色沉淀不在消失为终点（Ag2CrO4为砖红色）。回答下列问题：（1）装置中安全管的作用原理是。（2）用 NaOH 标准溶
14、液滴定过剩的HCl 时，应使用式滴定管，可使用的指示剂为。（3）样品中氨的质量分数表达式为。（4）测定氨前应该对装置进行气密性检验，若气密性不好测定结果将(填“偏高”或“偏低”)。（5）测定氯的过程中，使用棕色滴定管的原因是：滴定终点时，若溶液中c(Ag+)=2.0 10-5mol L-1，c(CrO42-)为 mol L-1 mol。（已知：Ksp(Ag2CrO4)=1.1210-12）(6)经测定，样品X 中钴、氨和氯的物质的量之比为1:6:3，钴的化合价为。制备X 的化学方文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2
15、HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10
16、ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档
17、编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y
18、2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R1
19、0 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3
20、文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R
21、3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3程式为：X 的制备过程中温度不能过高的原因是。36 化学选修 2：化学与技术（15 分）将海水淡化和与浓海水资源化结合起来是综合利用海水的重要途径之一。一般是先将海水淡化获得淡水，再从剩余的浓海水中通过一系列工艺提取其他产品。回答下列问题：（1）下列改进和优化海水综合利用工艺的设想和做法可行的是（填序号）。用混凝法获取淡水提高部分产品的质量优化提取产品的品种改进钾溴镁的提取工艺
22、（2）采用“空气吹出法”从浓海水中吹出Br2，并用纯碱吸收。碱吸收溴的主要反应是：Br2+Na2CO3+H2ONaBr+NaBrO3+6NaHCO3，吸收 1mol Br2时转移的电子为mol。（3）海水提镁的一段工艺流程如下图：浓海水的主要成分如下：该工艺过程中，脱硫阶段主要反应的离子方程式为，产品2 的化学式为，1L 浓海水最多可得到产品2 的质量为g。（4）采用石墨阳极不锈钢阴极电解熔融的氯化镁，发生反应的化学方程式为；电解时，若有少量水存在会造成产品镁的消耗，写出有关反应的化学方程式。37、化学 选修 3：物质结构与性质 周期表前四周期的元素a、b、c、d、e，原子序数依次增大。A 的
23、核外电子总数与其周期数相同，b 的价电子层中的未成对电子有3 个，c 的最外层电子数为其内层电子数的3 倍，d与 c 同族；e 的最外层只有1 个电子，但次外层有18 个电子。回答下列问题：（1）b、c、d 中第一电离能最大的是（填元素符号），e 的价层电子轨道示意图为。（2）a 和其他元素形成的二元共价化合物中，分子呈三角锥形，该分子的中心原子的杂化方式为；分子中既含有极性共价键、又含有非极性共价键的化合物是（填化学式，写出两种）。文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X
24、3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6
25、R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A
26、8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I
27、2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9
28、Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y
29、2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P
30、1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3（3）这些元素形成的含氧酸中，分子的中心原子的价层电子对数为3 的酸是；酸根呈三角锥结构的酸是。（填化学式）（4）e 和 c 形成的一种离子化合物的晶体结构如图1，则 e 离子的电荷为。（5）这 5 种元素形成的一种1：1 型离子化合物中，阴离子呈四面体结构；阳离子吴轴向狭长的八面体结构（如图2 所示）。该化合物中阴离子为，阳离子中存在的化学键类型有；该化合物加热时首先失去的组分是，判断理由是。38 化学 选修 5：有机化
31、学基础（15 分）立方烷（）具有高度的对称性、高致密性、高张力能及高稳定性等特点，因此合成立方烷及其衍生物成为化学界关注的热点。下面是立方烷衍生物I 的一种合成路线：回答下列问题：（1）C 的结构简式为，E 的结构简式为。（2）的反应类型为，的反应类型为。（3）化合物A 可由环戊烷经三步反应合成：反应 1 的试剂与条件为：反应 2 的化学方程式为：反应 3 可用的试剂为。文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 Z
32、C4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编
33、码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2
34、 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10
35、 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文
36、档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3
37、Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R
38、10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3（4）在 I 的合成路线中，互为同分异构体的化合物是（填化合物代号）。（5）I 与碱石灰共热可转化为立方烷，立方烷的核磁共振氢谱中有个峰。（6）立方烷经消化可得到六硝基立方烷，其可能的结构有种。答案7A 8 C 9B 10 D 11D 12C 13B 26（13 分）（1）大于0.0010 0.36mol L-1（2）a：大于反应正方向吸热，反应向吸热方向进行，故温度升高b：K2=(0.16molL-1)2/(0.020molL-1)=1.3molL-1(3)逆反应对气体分子数增大的反
39、应，增大压强平衡向逆反应方向移动27（15 分）（1）六 A 弱文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7
40、Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3
41、P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX
42、5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6
43、V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4
44、D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:
45、CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3（2）PbO2+4HCl(浓)=PbCl2+Cl2+2H2O（3）PbO+ClO-=PbO2+Cl-Pb2+2H2O-2e-=PbO2+4H+石墨上包上铜镀层Pb2+2e-=Pb不能有效利用Pb2+（
46、4）x=2-16%0.4239=1.4 nm=6.04.0=3228（15 分）（1）瓶 A 中的压力过大时，安全管中的液面上升，使A 瓶中的压力稳定。（2）碱酚酞（或甲基红）（3）100%(c1V1-c2V2)10-317 w（4）偏低（5）防止硝酸银见光分解2.8 10-3（6）+3 2CoCl2+NH4Cl+10NH3+H2O2=2Co(NH3)6Cl3+2H2O 温度过高过氧化氢分解，氨气逸出36 化学选修 2：化学与技术（15 分）（1）（2）35（3）Ca2+SO42-=CaSO4 Mg(OH)2 69.6 (4)22ClMgMgCl电解222HOHMgOH2Mg）（高温37、化学
47、 选修 3：物质结构与性质（15 分）(1)N (2)sp3H2O2N2H4（3）HNO2 HNO3H2SO3（4）+1（5）H2SO4共价键和配位键H2O H2O 与 Cu2+的配位键比NH3与 Cu2+的弱38 化学 选修 5：有机化学基础（15 分）（1）（2）取代反应消去反应（3）Cl2/光照O2/Cu（4）G 和 H（5）1 文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5
48、B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V
49、7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D
50、3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:CX5B9Q6R3Y2 HF6V7Y2A8R10 ZC4D3P1I2X3文档编码:C