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1、-作者xxxx-日期xxxxMP159(GH159)合金研究-上海商虎合金技术【精品文档】MP159钴基高温合金简介编制单位上海商虎编制时间2019年03月页 次共三页 蔡 婷、潘龙虎、孙 军、丁春华（上海商虎有色金属有限公司，上海 201708）【供应品种】GH159冷轧带材、GH159冷轧板材、GH159棒材、GH159丝材技术顾问：潘工联系电话：工作传真：021-67859199公司地址：上海市青浦区华新镇一、GH159概述 GH159合金是在国外多相钴基高温合金（MP合金）的基础上发展起来的一种新型高强度多相钴基高温合金。它的主要特点是：利用冷变形首先在面心立方基体中诱发产生交叉网状分
2、布的片状相来阻止位错的长程运动而产生强化，再经过时效处理析出弥散的Ni3X相补充强化。该合多金具有超高强度、良好的塑韧性和高的应力腐蚀抗力等综合性能，并且在650的高温下仍能保持其高强度的特性。该合金不仅可广泛用于航空发动机的高温紧固螺栓等零件，也可用于应力腐蚀环境下（如海洋大气环境）服役的飞机用超高强度紧固件。供应的主要品种是冷拉棒材。1.1 GH159材料牌号 GH159。1.2 GH159相近牌号1.3 GH159材料的技术标准Q/6S992-1992高温紧固件用GH159合金冷拉棒材(北京航空材料研究所)C3S284-1993高温紧固件GH159合金冷拉棒材协上五高28-1993高温紧
3、固件GH159合金冷拉棒材1.4 GH159化学成分 见表1-1。 表1-1 %CCrNiCoMoFeTiAlNbBMnSiPS不大于1820余3438688100.02 1.5 GH159热处理制度 固溶处理10401055,48h,水冷+在室温进行48%1%的冷拔变形时效处理650675，44.5h，空冷。 1.6 GH159品种规格与供应状态 可以供应d525mm的冷拉棒材，供应状态为冷拔态。 1.7GH159熔炼与铸造工艺 采用真空感应加真空电弧重熔的双联生产工艺。 1.8GH159应用概况与特殊要求 该合金主要用于航空发动机的紧固件，在600下性能稳定，可长期使用。是目前综合性能良好
4、航空发动机紧固件材料。 合金主要是经过冷变形诱发产生大量网状分布的相进行强化。因此，对冷拔变形的工艺参数要严格控制。变形量过小，强度不足；变形量太大，强度升高，但塑性降低。实践证明，当冷变形量控制在下限时合金具有较好的综合性能。二、GH159物理及化学性能2.1 GH159热性能2.1.1 GH159熔化温度范围 熔点13181。2.1.2 GH159热导率 见表2-1。 表2-11/100200300400500600700800/(W/m)冷拔状态冷拔时效状态-2.1.3 GH159线膨胀系数 见表2-2(冷拔时效状态)。 表2-23/251002520025300254002550025
5、6002570025800/10-6-132。2.3 GH159电性能 合金的电阻率见表2-3。 表2-31/2510025200253002540025500256002570025800/10-6-12.4 GH159磁性能 合金在252。2.5 GH159化学性能 2.5.1 GH159耐腐蚀性能 该合金具有极好的抗缝隙腐蚀和应力腐蚀开裂的能力。在典型的氯化铁实验中未发现缝隙腐蚀和点蚀。在擦盐试验中未发生损坏。交替浸渍证明该合金具有良好的抗氢脆和应力腐蚀开裂的能力。四、GH159组织结构4.1GH159相变温度+两相区温度范围为540700,540以下的相为亚稳态。4.2GH159时间-
6、温度-组织转变曲线4.3GH159合金组织结构合金在上临界温度(约700)以上为稳定的面心立方相,在下临界温度以下(约540)为稳定的密排六方相;两温度之间为+的两相区。当合金从上临界温度冷却到室温时可保持亚稳定态的相。当在室温下进行冷变形时可诱发相到相的马氏体型转变。因此,合金经固溶处理后全部为亚稳定的相,在冷变形过程中部分相发生马氏体相变转变为稳定的相。所生成的相为薄片状,在面心立方的相晶粒内呈交叉网状分布。在随后的时效过程中又在亚稳定的相中析出Ni3X相47。上海商虎有色金属有限公司生产范围.Nickel 200 UNS N02200Nickel 201 UNS N02201ASTM B
7、-168, ASTM B-829, ASTM B-775, ASTM B-751, ASTM B-161, ASTM B-725, ASTM B-163, ASTM B-730, ASTM B-162, ASTM B-160, ASTM B-564, ASTM B-366, ASME SB-168, ASME SB-829, ASME SB-775, ASME SB-751, ASME SB-161, ASME SB-725, ASME SB-163, ASME SB-730, ASME SB-162, ASME SB-160, ASME SB-564, ASME SB-366, AMS555
8、3ALLOY 400 BS 3076 NA13, QQ-N-281 Class A, ASTM B164Monel 400?, Nickelvac? 400, Nicorros? 400Monel R405? UNS N04405ALLOY K-500 BS 3076 NA18, QQ-N-286, ASTM B865ASTM B-165, ASTM B-725, ASTM B-163, ASTM B-127, ASTM B-164, ASTM B-564, ASTM B-366, ASTM B-865, ASTM B-829, ASTM B-775, ASTM B-165, ASTM B-7
9、30, ASTM B-751, ASME SB-165, ASME SB-725, ASME SB-163, ASME SB-127, ASME SB-164, ASME SB-564, ASME SB-366, ASME SB-865, ASME SB-829, ASME SB-775, ASME SB-165, ASME SB-730, ASME SB-751, AMS4544ALLOY 600 UNS N06600Inconel 600?, Nickelvac? 600, Ferrochronin? 600ALLOY 617 UNS N06617Inconel 617?, Nicrofe
10、r 5520? ALLOY 625 UNS N06625Inconel 625?, Chronin? 625, Altemp? 625, Haynes? 625, Nickelvac? 625, Nicrofer? 6020Alloy 718 UNS N07718Inconel 718?, Nicrofer? 5219, Allvac? 718, Haynes? 718, Altemp? 718ASTM B-168, ASTM B-443, ASTM B-166, ASTM B-446, ASTM B-637, ASTM B-167, ASTM B-829, ASTM B-517, ASTM
11、B-775, ASTM B-444, ASTM B-705, ASTM B-163, ASTM B-516, ASTM B-751, ASTM B-704, ASTM B-366, ASTM B-564 ASME SB-168, ASME SB-443, ASME SB-166, ASME SB-446, ASME SB-637, ASME SB-167, ASME SB-829, ASME SB-517, ASME SB-775, ASME SB-444, ASME SB-705, ASME SB-163, ASME SB-516, ASME SB-751, ASME SB-704, ASM
12、E SB-366, ASME SB-564, AMS5540, AMS5870, AMS5715, AMS5889, AMS5888, AMS5887, AMS5596, AMS5662, AMS5663, AMS5664, AMS5542, AMS5598, AMS5667, AMS5599, AMS5879, AMS5666Cast And Wrought Nickel-Cobalt-Iron Base SuperAlloys for Gas Turbine Engine, Turbine Blades, Industrial Gas Turbine RotorsIN738 LC, IN7
13、13 LC, IN939, IN100, B1900, RENE80, RENE88, RENE95IN738LC, IN713LC, IN-939, IN-100, B-1900, RENE-80, RENE-88, RENE-95IN 738 LC, IN 713 LC, IN 939, IN 100, B 1900, RENE 80, RENE 88, RENE 95PWA1422, PWA1484, PWA1426, C1023, MARM002, X45, FSX414PWA 1422, PWA 1484, PWA 1426, C 1023, MARM002, X 45, FSX 4
14、14ALLOY X-750 UNS N07750Inconel X750?, Haynes X750?, Pyromet? X750, Nickelvac? X750, Nicrofer? 7016ALLOY 800 UNS N08800Incoloy 800H?, Ferrochronin? 800, Nickelvac? 800, Nicrofer? 3220Incoloy 800H? UNS N08810Incoloy 800HT? UNS N08811ALLOY 825 UNS N08825Incoloy 825?, Nickelvac? 825, Nicrofer? 4221ASTM
15、 B-409, ASTM B-424, ASTM B-408, ASTM B-425, ASTM B-407, ASTM B-829, ASTM B-514, ASTM B-775, ASTM B-423, ASTM B-705, ASTM B-515, ASTM B-751, ASTM B-163, ASTM B-704, ASTM B-366, ASTM B-564, ASME SB-409, ASME SB-424, ASME SB-408, ASME SB-425, ASME SB-407, ASME SB-829, ASME SB-514, ASME SB-775, ASME SB-
16、423, ASME SB-705, ASME SB-515, ASME SB-751, ASME SB-163, ASME SB-704, ASME SB-366, ASME SB-564, AMS5871, AMS5660, AMS5661Alloy C22 UNS N06022Hastelloy C22?, Inconel? 22, Nicrofer? 5621Alloy C276 UNS N10276Hastelloy C276?, Nickelvac? HC-276, Inconel? C276, Nicrofer? 5716Alloy B2 UNS N10665Hastelloy B
17、2?, Nimofer? 6928ALLOY X UNS N06002Hastelloy X?, Nickelvac? HX, Nicrofer? 4722, Altemp? HX, Inconel? HXASTM B-575, ASTM B-333, ASTM B-435, ASTM B-574, ASTM B-335, ASTM B-572, ASTM B-622, ASTM B-619, ASTM B-775, ASTM B-829, ASTM B-516, ASTM B-626, ASTM B-751, ASTM B-366, ASTM B-564, ASME SB-575, ASME
18、 SB-333, ASME SB-435, ASME SB-574, ASME SB-335, ASME SB-572, ASME SB-622, ASME SB-619, ASME SB-775, ASME SB-829, ASME SB-516, ASME SB-626, ASME SB-751, ASME SB-366, ASME SB-564, AMS5530, AMS5750, AMS5894, AMS5548, AMS5617, AMS5750Maraging 250 / Maraging C250 / Vascomax C250? UNS K92890Maraging 300 /
19、 Maraging C300 / Vascomax C300? UNS K93120Vascomax? 300, Maraging C300Maraging 350 / Maraging C350 / Vascomax C350?Vascomax? 350Custom? 450 XM-25 / CUSTOM-450 XM25Rene 41? UNS N07041Rene 41?, Allvac Rene? 41, Haynes? R-41, Udimet? R41Multimet N155? - UNS R30155Haynes 25? UNS R30605 Alloy L605Haynes
20、188? - UNS R30188Haynes? 188, Udimet? 188 Conicro? 4023Waspalloy? UNS N07001Waspalloy?, Allvac? Waspalloy?MP35N? UNS R30035MP159? UNS R30159Cobalt Alloy 6B UNS R30006Stellite 6B?Alloy 36 UNS K93600Invar 36?, Nilo 36?, Pernifer? 36Invar 42 / Nilo 42? UNS K94200Invar 42?, Nilo 42?Kovar? UNS K94610UNS
21、N08367 Alloy AL6XN?NI-SPAN-C 902? UNS N09902Alloy A286? UNS S66286 (UNS K66286) Din 1.4980 Altemp? A286 Pyromet? Alloy A-286Alloy 330? UNS N08330Alloy 330, RA330?, Incoloy? 330, Nicrofer? 3718CP Titanium Grade 1CP Titanium Grade 2Titanium Grade 5/Titanium 6AL4V/Ti6Al4VEli Surgical Grade, Orthopaedic
22、 ImplantsTitanium Ti-6Al-4V ELI Annealed Extra Low Interstitial UNS R56401 (ELI)Titanium Alpha-Beta Alloy Biomaterials, Biomedical Implants, BiocompatiblityTitanium Alloy Ti-6Al-4VEli ISO5832-3 Ti6Al4VEli ASTM F136 ISO 5832-3Aluminium Alloy 2024 Temper T351, Alloy 6061 Temper T6, Alloy 6061 Temper T
23、651Aluminium Alloy 7075 Temper T651, Alloy 7075 Temper T7351, Alloy 7050 Temper T7451Aluminium Alloy 7050 Temper T7651, Alloy 7475 Temper T7351, MIC-6, ALCA PLUS/MAXTemperature Sensitive Alloy, Fusible Alloy, Low Melting Alloy, Anode Alloy, Babbitt AlloyBallast Alloy, Bismuth Alloy, Bullet Alloy, Ho
24、bby Casting Alloy, Jewelry/Pewter AlloyLead Based Alloy, Lead Free Alloy, Lure Making Alloy, Solder Alloy, Spin Casting AlloyTin Based Alloy, Zinc Alloy, Fusible Alloy Contain Bismuth, Lead, Tin, Cadmium, Indium15-5PH UNS S15500 15/5PH17-4PH UNS S17400 17/4PH17-7PH UNS S17700 17/4PHNITRONIC 40? UNS
25、S21904NITRONIC 50? UNS S20910 XM-19NITRONIC 60? UNS S21800Nimonic 75 UNS N06075Nimonic 80A UNS N07080Nimonic 90 UNS N07090Nimonic 263 UNS N07263Incoloy DSHastelloy C4 UNS N06455Nitralloy 135 MOD, Nitralloy 135MOD, Nitralloy 135 ModifiedAlloy 135 MOD, Nitriding Alloy 135 MOD, Alloy 135 MODIFIEDHeat R
26、esistant in grades SUS310, 310S, 310H, SUS309, SUS309SStainless Steel TP310, TP310S, TP310H, TP309, TP309SAISI 440C SUS440C AISI-440C SUS 440C DIN-1.4125 UNS-S44004AISI 422 UNS S42200 JIS SUH 616 Din 1.4935 ASTM A565 AMS 5655 Martensitic Stainless SteelAlloy 904L UNS N08904 Din 1.4539 UB-6 URANUS B6
27、 UB6 AISI 904L254 SMO UNS S31254 254SMO Din 1.4547 SMO 254ASTM A182 Grade F44 UNS S31254 EN 1.4547 X1CrNiMoCuN20-18-7Sanicro 28 UNS N08028 SANICRO 28 Din 1.4563 Sanicro-28Alloy 20 UNS N08020 Din 2.4660 CARPENTER 20?, 20Cb-3?Copper Nickel 90/10 UNS C70600 CuNi 90/10 Cupro Nickel 90-10Copper Nickel 70
28、/30 UNS C71500 CuNi 70/30 Cupro Nickel 70-30Duplex 2205 UNS S31803 ASTM A182 F-51 / F-60 318LN DIN 1.4462 SAF2205 SA182 F51 / F60Duplex ASTM A182 Grade F60 / ASME SA182 Grade F60 NACE & Norsok ApprovedDuplex SAF2205 SANMAC UNS S32205 URANUS? 45N PREN = 33 or 34 A182 F51 (329LN) / F60Duplex 2205, Dup
29、lex SAF2205, Duplex SAF 2205, UNS S31803/S32205, Din 1.4462 EN 10088-3Duplex SAF2205 SANMAC, URANUS 45N, PREN33, PREN34, PREN35, PREN36Duplex 329 F52 UNS S32950 ASTM A182 F-52 SA182 F52Super Duplex SAF2507 UNS S32750 DIN 1.4410 EN10088 URANUS 47N(+) PREN41 A182-F53Super Duplex UNS S32760 F55 ASTM A1
30、82 F-55 SA182 F55 DIN 1.4501 UNS 32760SA213 T91/T-91, SA213 T22/T-22, SA213 T11/T-11, SA213 T5/T-5, SA213 T9/T-9 Seamless Tubes for Boiler, Superheater & Heat-Exchanger SA213 TP347H, SA213 TP321H, SA213 TP304H, SA213 TP304L, SA213 TP304, SA213 TP316H, SA213 TP316, SA213 TP316L, SA213 TP316Ti, SA213
31、TP317L Seamless Tubes for Boiler, Superheater & Heat-ExchangerASME SA516 Grade-70 Pressure Vessel Plates for Low Temperature Service, ASME SA515 Grade-70 Pressure Vessel Plates for High Temperature Service, ASME SA516 Grade-60 Boiler Plates, ASME SA515 Grade-60 Boiler Plates, ASTM A516-60 Pressure Vessel Plates ASTM A515-60 Pressure Vessel Plates ASTM A515-70 Boiler Plates ASTM A516-70 Boiler Plates【精品文档】